Catalytic oxidation of CO over CuO@TiO2 catalyst: The relationship between activity and adsorption performance

IF 1.5 4区材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY

Micro & Nano Letters Pub Date : 2024-11-10 DOI:10.1049/mna2.70005

Yuan Bai, Ping Shi, Xin Zhang, Fei Wei, Liguo Chen, Jing Song, Jian Qiu, Bin Chen, Hong Zhu, Haitao Xu

{"title":"Catalytic oxidation of CO over CuO@TiO2 catalyst: The relationship between activity and adsorption performance","authors":"Yuan Bai, Ping Shi, Xin Zhang, Fei Wei, Liguo Chen, Jing Song, Jian Qiu, Bin Chen, Hong Zhu, Haitao Xu","doi":"10.1049/mna2.70005","DOIUrl":null,"url":null,"abstract":"The emission of CO toxic gases seriously endangers environmental safety and human health. At present, the use of catalysts for catalytic oxidation of CO has become the mainstream research direction. In this study, CuO@TiO2 catalysts with different ratios were prepared by solvent hydrothermal method, and the effects of reaction pretreatment temperature and other factors on the catalytic oxidation performance of CO were investigated. The experimental results show that the catalyst can achieve 100% conversion of CO at 115°C under the condition of pretreament at 350°C for 2 h. This excellent performance is due to the uniform distribution of the active component on the surface of the TiO2 support, and the large pore structure constructed by the solvent hydrothermal method enhances the adsorption and activation of CO. This work provides an idea for the preparation of CO oxidation catalysts.","PeriodicalId":18398,"journal":{"name":"Micro & Nano Letters","volume":"19 6","pages":""},"PeriodicalIF":1.5000,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/mna2.70005","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Micro & Nano Letters","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1049/mna2.70005","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

Abstract

The emission of CO toxic gases seriously endangers environmental safety and human health. At present, the use of catalysts for catalytic oxidation of CO has become the mainstream research direction. In this study, CuO@TiO₂ catalysts with different ratios were prepared by solvent hydrothermal method, and the effects of reaction pretreatment temperature and other factors on the catalytic oxidation performance of CO were investigated. The experimental results show that the catalyst can achieve 100% conversion of CO at 115°C under the condition of pretreament at 350°C for 2 h. This excellent performance is due to the uniform distribution of the active component on the surface of the TiO₂ support, and the large pore structure constructed by the solvent hydrothermal method enhances the adsorption and activation of CO. This work provides an idea for the preparation of CO oxidation catalysts.

Abstract Image

查看原文本刊更多论文

CuO@TiO2 催化剂催化氧化 CO：活性与吸附性能之间的关系

CO 有毒气体的排放严重危害环境安全和人类健康。目前，利用催化剂催化氧化 CO 已成为主流研究方向。本研究采用溶剂水热法制备了不同配比的 CuO@TiO2 催化剂，考察了反应预处理温度等因素对 CO 催化氧化性能的影响。实验结果表明，该催化剂在 350℃ 预处理 2 h 的条件下，115℃ 时 CO 的转化率可达 100%。这种优异的性能得益于活性组分在 TiO2 载体表面的均匀分布，以及溶剂水热法构建的大孔隙结构增强了对 CO 的吸附和活化。这项工作为制备 CO 氧化催化剂提供了一种思路。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Micro & Nano Letters 工程技术-材料科学：综合

CiteScore

3.30

自引率

0.00%

发文量

审稿时长

2.8 months

期刊介绍： Micro & Nano Letters offers express online publication of short research papers containing the latest advances in miniature and ultraminiature structures and systems. With an average of six weeks to decision, and publication online in advance of each issue, Micro & Nano Letters offers a rapid route for the international dissemination of high quality research findings from both the micro and nano communities. Scope Micro & Nano Letters offers express online publication of short research papers containing the latest advances in micro and nano-scale science, engineering and technology, with at least one dimension ranging from micrometers to nanometers. Micro & Nano Letters offers readers high-quality original research from both the micro and nano communities, and the materials and devices communities. Bridging this gap between materials science and micro and nano-scale devices, Micro & Nano Letters addresses issues in the disciplines of engineering, physical, chemical, and biological science. It places particular emphasis on cross-disciplinary activities and applications. Typical topics include: Micro and nanostructures for the device communities MEMS and NEMS Modelling, simulation and realisation of micro and nanoscale structures, devices and systems, with comparisons to experimental data Synthesis and processing Micro and nano-photonics Molecular machines, circuits and self-assembly Organic and inorganic micro and nanostructures Micro and nano-fluidics