Lewis Acid-Catalyzed Isomerization of Donor-Acceptor Cyclobutanes in the Presence of Thiourea: A New Efficient Route to 2- Arylallylmalonates

IF 1.9 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

ChemistrySelect Pub Date : 2024-11-08 DOI:10.1002/slct.202404202

Ruixin Zhao, Yanqing Zhang, Jintao Zhang, Prof. Zuliang Chen

引用次数: 0

Abstract

A straightforward access to various substituted 2-arylallylmalonates from readily available donor-Acceptor (D-A) cyclobutanes catalyzed by Al(OTf)₃ in the presence of thiourea is reported. This is a new and convenient approach for isomerization of donor-acceptor cyclobutanes into 2-arylallylmalonates.

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硫脲存在时路易斯酸催化的供体-受体环丁烷异构化：2- 芳基丙二酸酯的高效新途径

据报道，在 Al(OTf)3 催化下，在硫脲存在的条件下，可以从容易获得的供体-受体（D-A）环丁烷直接获得各种取代的 2-芳基烯丙基丙二酸酯。这是一种将供体-受体环丁烷异构化为 2-芳基烯丙基丙二酸酯的全新而便捷的方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

ChemistrySelect Chemistry-General Chemistry

CiteScore

3.30

自引率

4.80%

发文量

1809

审稿时长

1.6 months

期刊介绍： ChemistrySelect is the latest journal from ChemPubSoc Europe and Wiley-VCH. It offers researchers a quality society-owned journal in which to publish their work in all areas of chemistry. Manuscripts are evaluated by active researchers to ensure they add meaningfully to the scientific literature, and those accepted are processed quickly to ensure rapid online publication.