Antimicrobial textiles based on photocrosslinked poly(ethylene-co-acrylic acid)†

Yimin Zeng and Michael O. Wolf
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Abstract

Photocrosslinking of a series of amine-containing poly (ethylene-co-acrylic acids) (PEAAs) on textile surfaces by reaction of photogenerated singlet oxygen at the amine groups to form imines is reported. The materials are hydrophilic and show antimicrobial activity. Modified PEAAs with 3 different lengths of side chains are synthesized to study the effect of varying side chain length on polymer photooxidative crosslinking and antimicrobial activity. Materials with longer side chains show elimination of E. coli and MRSA by contact lysis which is enhanced under irradiation with green light.

Abstract Image

基于光交联聚(乙烯-丙烯酸)†的抗菌纺织品
据报道,一系列含胺的聚(乙烯-丙烯酸)(PEAAs)通过光产生的单线态氧在胺基上反应生成亚胺,从而在纺织品表面发生光交联。这些材料具有亲水性并显示出抗菌活性。为了研究不同侧链长度对聚合物光氧化交联和抗菌活性的影响,我们合成了具有 3 种不同侧链长度的改性 PEAAs。具有较长侧链的材料可通过接触裂解消除大肠杆菌和 MRSA,而在绿光照射下,这种效果更强。
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