Influence of Process Conditions During Aqueous and Direct Recycling of NMC811 Cathodes.

IF 7.5 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
ChemSusChem Pub Date : 2024-11-14 DOI:10.1002/cssc.202401803
Felix Nagler, Leonhard Kolb, Nino Christian, Andreas Flegler, Michael Hofmann, Guinevere A Giffin
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引用次数: 0

Abstract

This study investigated the impact of various process conditions on the aqueous, direct recycling of LiNi0.8Mn0.1Co0.1O2 (NMC811) cathodes. Three model systems were used. The first system assumes that the current collector delamination is performed in a dry environment without the use of water as a process medium. Consequently, the NMC811 is only exposed to water during classification, where no aluminum foil is present. The second model system assumes that the current collector delamination occurs in water. Therefore, the NMC811 is exposed to water in the presence of aluminum foil. Due to the pH increase caused by the Li+/H+ exchange reaction, the pH value surpasses the stability window of the aluminum-oxide passivation layer (pH 4.5-8.5), resulting in the deposition of aluminum-containing species on the NMC811 surface. The third model system is identical to the second, with the exception that H3PO4 is added. This causes the pH to decrease and prevents corrosion of the aluminum foil. The findings reveal that process conditions significantly affect the surface chemistry on NMC811, influencing electrochemical performance. Notably, aluminum-containing species increase polarization. Heat treatment simulating regeneration led to cation mixing as surface species diffused into the NMC811 bulk structure, highlighting the need to control recycling process conditions.

NMC811 阴极水循环和直接循环过程中工艺条件的影响。
本研究探讨了各种工艺条件对水基直接回收镍钴锰酸锂(NMC811)阴极的影响。 使用了三个模型系统。第一个系统假定电流收集器分层是在干燥环境中进行的,不使用水作为工艺介质。因此,NMC811 只在分级过程中接触到水,而在分级过程中没有铝箔存在。第二个模型系统假定电流收集器分层是在水中进行的。因此,NMC811 会在有铝箔的情况下接触到水。由于 Li+/H+ 交换反应导致 pH 值升高,pH 值超过了氧化铝钝化层的稳定窗口(pH 值为 4.5-8.5),从而导致含铝物沉积在 NMC811 表面。第三个模型系统与第二个相同,不同之处在于加入了 H3PO4。这导致 pH 值降低,防止了铝箔的腐蚀。研究结果表明,工艺条件会显著影响 NMC811 的表面化学性质,从而影响电化学性能。值得注意的是,含铝物种会增加极化。模拟再生的热处理会导致阳离子混合,因为表面物种会扩散到 NMC811 的主体结构中,这突出了控制回收工艺条件的必要性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
ChemSusChem
ChemSusChem 化学-化学综合
CiteScore
15.80
自引率
4.80%
发文量
555
审稿时长
1.8 months
期刊介绍: ChemSusChem Impact Factor (2016): 7.226 Scope: Interdisciplinary journal Focuses on research at the interface of chemistry and sustainability Features the best research on sustainability and energy Areas Covered: Chemistry Materials Science Chemical Engineering Biotechnology
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