Enhancing Precision and Durability of Built-In Cu-Li Reference Electrodes in Lithium-Ion Batteries: A Critical Review

IF 19.3 1区 材料科学 Q1 CHEMISTRY, PHYSICAL
Zhiguo Zhang, Yiding Li, Xueqing Min, Dongsheng Ren, Youzhi Song, Li Wang*, Hong Zhao* and Xiangming He*, 
{"title":"Enhancing Precision and Durability of Built-In Cu-Li Reference Electrodes in Lithium-Ion Batteries: A Critical Review","authors":"Zhiguo Zhang,&nbsp;Yiding Li,&nbsp;Xueqing Min,&nbsp;Dongsheng Ren,&nbsp;Youzhi Song,&nbsp;Li Wang*,&nbsp;Hong Zhao* and Xiangming He*,&nbsp;","doi":"10.1021/acsenergylett.4c0243110.1021/acsenergylett.4c02431","DOIUrl":null,"url":null,"abstract":"<p >The reference electrode (RE), integrated as a sensor within lithium-ion batteries (LIBs), offers real-time insights into the electrochemical properties of individual electrodes, which makes it an ideal indicator for monitoring the working state of LIBs. Nevertheless, most built-in REs in LIBs face significant challenges that limit their application as precise and durable sensors for effective battery management, relegating them to being rough and temporary indicators in research settings. This Review delves into the latest advances in enhancing the accuracy and longevity of lithium metal deposited on Cu (Cu-Li) REs. It explores the underlying causes and factors contributing to measurement inaccuracies. Finally, the Review puts forth strategies to overcome these challenges in three-electrode LIBs. Gaining a comprehensive understanding of the intrinsic behaviors of LIBs, REs, and their interactions is pivotal for developing high-precision REs, thereby accelerating the innovation of new and safer LIB technologies.</p>","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"9 11","pages":"5647–5669 5647–5669"},"PeriodicalIF":19.3000,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Energy Letters ","FirstCategoryId":"88","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsenergylett.4c02431","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

Abstract

The reference electrode (RE), integrated as a sensor within lithium-ion batteries (LIBs), offers real-time insights into the electrochemical properties of individual electrodes, which makes it an ideal indicator for monitoring the working state of LIBs. Nevertheless, most built-in REs in LIBs face significant challenges that limit their application as precise and durable sensors for effective battery management, relegating them to being rough and temporary indicators in research settings. This Review delves into the latest advances in enhancing the accuracy and longevity of lithium metal deposited on Cu (Cu-Li) REs. It explores the underlying causes and factors contributing to measurement inaccuracies. Finally, the Review puts forth strategies to overcome these challenges in three-electrode LIBs. Gaining a comprehensive understanding of the intrinsic behaviors of LIBs, REs, and their interactions is pivotal for developing high-precision REs, thereby accelerating the innovation of new and safer LIB technologies.

Abstract Image

提高锂离子电池内置铜锂离子参比电极的精度和耐用性:批判性评论
集成在锂离子电池(LIB)中作为传感器的参比电极(RE)可以实时了解单个电极的电化学特性,因此是监测锂离子电池工作状态的理想指标。然而,锂离子电池中的大多数内置可再生能源都面临着重大挑战,限制了它们作为精确、耐用的传感器在有效电池管理方面的应用,使它们只能作为研究环境中粗糙的临时指标。本综述深入探讨了在提高铜(Cu-Li)锂金属沉积可再生能源的精度和寿命方面取得的最新进展。它探讨了导致测量不准确的根本原因和因素。最后,该综述提出了克服三电极锂电池所面临的这些挑战的策略。全面了解 LIB、RE 及其相互作用的内在行为对于开发高精度 RE 至关重要,从而加速创新更安全的新型 LIB 技术。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
ACS Energy Letters
ACS Energy Letters Energy-Renewable Energy, Sustainability and the Environment
CiteScore
31.20
自引率
5.00%
发文量
469
审稿时长
1 months
期刊介绍: ACS Energy Letters is a monthly journal that publishes papers reporting new scientific advances in energy research. The journal focuses on topics that are of interest to scientists working in the fundamental and applied sciences. Rapid publication is a central criterion for acceptance, and the journal is known for its quick publication times, with an average of 4-6 weeks from submission to web publication in As Soon As Publishable format. ACS Energy Letters is ranked as the number one journal in the Web of Science Electrochemistry category. It also ranks within the top 10 journals for Physical Chemistry, Energy & Fuels, and Nanoscience & Nanotechnology. The journal offers several types of articles, including Letters, Energy Express, Perspectives, Reviews, Editorials, Viewpoints and Energy Focus. Additionally, authors have the option to submit videos that summarize or support the information presented in a Perspective or Review article, which can be highlighted on the journal's website. ACS Energy Letters is abstracted and indexed in Chemical Abstracts Service/SciFinder, EBSCO-summon, PubMed, Web of Science, Scopus and Portico.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信