{"title":"Peach gum-based polyimine networks with water resistant, high strength and recycling performances","authors":"Ting Huang, Xianjie Pan, Aoqian Xi, Wenpei Chen, Ningning Zhang, Yanning Zeng","doi":"10.1016/j.polymer.2024.127845","DOIUrl":null,"url":null,"abstract":"The preparation of the polyimine (PI) networks from renewable feedstocks has attracted increasing attention due to the degradability and self-healing capabilities of PI networks, which contribute to sustainable development. However, most of bio-based PI networks possess poor environmental stability and mechanical strength. Herein, natural peach gum w·as employed to construct water-resistant bio-based PI networks with high performances, by the curing reaction of Schiff base between 4-aminobenzoic acid grafted peach gum polysaccharide and vanillin-derived difunctionalized aldehyde. The resultant polyimine networks (PGBV) exhibit high tensile strength and high Young’s modulus, due to their unique network structures. Moreover, PGBV-100 demonstrates excellent hydrophobicity, welding, self-healing and reprocessing abilities. Furthermore, PGBV-100 can completely degrade in an aqueous solution of HCl (0.1 M), enabling closed-loop recycling. In this work, a research strategy for constructing bio-based PI networks with high performances is presented and the resultant PGBV networks show promising potential application as materials for transportation and building materials.","PeriodicalId":405,"journal":{"name":"Polymer","volume":null,"pages":null},"PeriodicalIF":4.1000,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1016/j.polymer.2024.127845","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
The preparation of the polyimine (PI) networks from renewable feedstocks has attracted increasing attention due to the degradability and self-healing capabilities of PI networks, which contribute to sustainable development. However, most of bio-based PI networks possess poor environmental stability and mechanical strength. Herein, natural peach gum w·as employed to construct water-resistant bio-based PI networks with high performances, by the curing reaction of Schiff base between 4-aminobenzoic acid grafted peach gum polysaccharide and vanillin-derived difunctionalized aldehyde. The resultant polyimine networks (PGBV) exhibit high tensile strength and high Young’s modulus, due to their unique network structures. Moreover, PGBV-100 demonstrates excellent hydrophobicity, welding, self-healing and reprocessing abilities. Furthermore, PGBV-100 can completely degrade in an aqueous solution of HCl (0.1 M), enabling closed-loop recycling. In this work, a research strategy for constructing bio-based PI networks with high performances is presented and the resultant PGBV networks show promising potential application as materials for transportation and building materials.
由于聚酰亚胺(PI)网络具有可降解性和自愈能力,有助于可持续发展,因此利用可再生原料制备聚酰亚胺(PI)网络日益受到关注。然而,大多数生物基 PI 网络的环境稳定性和机械强度较差。本文利用天然桃胶,通过 4-aminobenzoic acid 接枝桃胶多糖与香兰素衍生的双官能团醛之间的希夫碱固化反应,构建了具有高性能的防水生物基 PI 网络。由于其独特的网络结构,生成的聚亚胺网络(PGBV)具有很高的拉伸强度和杨氏模量。此外,PGBV-100 还具有出色的疏水性、焊接性、自愈性和再加工能力。此外,PGBV-100 还能在盐酸(0.1 M)水溶液中完全降解,从而实现闭环回收。本研究提出了一种构建高性能生物基 PI 网络的研究策略,所得到的 PGBV 网络作为运输和建筑材料的材料具有广阔的应用前景。
期刊介绍:
Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics.
The main scope is covered but not limited to the following core areas:
Polymer Materials
Nanocomposites and hybrid nanomaterials
Polymer blends, films, fibres, networks and porous materials
Physical Characterization
Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films
Polymer Engineering
Advanced multiscale processing methods
Polymer Synthesis, Modification and Self-assembly
Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization
Technological Applications
Polymers for energy generation and storage
Polymer membranes for separation technology
Polymers for opto- and microelectronics.