High triboelectrification and charge collection efficiency of direct current triboelectric nanogenerator achieved by tri-synergistic enhancement strategy

IF 51.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Shuyan Xu, Jian Wang, Chuncai Shan, Kaixian Li, Huiyuan Wu, Gui Li, Shaoke Fu, Qionghua Zhao, Yi Xi, Chenguo Hu
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引用次数: 0

Abstract

Direct current triboelectric nanogenerator (DC-TENG) utilized air-breakdown effect to collect triboelectrification charges from dielectric tribo-layers, providing a new type of mechanical energy harvesting mode for TENGs, which has demonstrated its high efficiency in energy conversion process. However, boosting the output performance based on structure designs and material modifications still meets great challenges. Herein, we propose a ternary dual-DC-TENG (TDD-TENG) with a triple synergistic enhancement mechanism. The strategies include the space optimization using multiple-unit structure on slider by seamlessly arranging PTFE/PA/electrode to realize maximized space utilization, ternary dielectric material selection by adopting PTFE, PA and PU foam as the tribo-layers with the spontaneously introduced PTFE powder on PU foam to achieve a higher triboelectrification effect and surface lubrication, and bottom electrode design to collect charges unreached by charge collection electrodes (CCEs) on slider forming a dual-DC output. Consequently, TDD-TENG achieves the average power density of 18.37 W m-2, which is the highest in sliding mode DC-TENGs. In addition, the output charge density of rotary TDD-TENG reaches 7.3 mC m-2 at an ultra-low speed of 5 rpm. This work provides a new method to improve output power from structure design and material modification for DC-TENGs.
通过三协同增强策略实现直流三电纳米发电机的高三电化和电荷收集效率
直流三电纳米发电机(DC-TENG)利用空气击穿效应从电介质三电层收集三电化电荷,为三电纳米发电机提供了一种新型的机械能收集模式,在能量转换过程中表现出高效率。然而,基于结构设计和材料改性提高输出性能仍面临巨大挑战。在此,我们提出了一种具有三重协同增强机制的三元双直流-TENG(TDD-TENG)。其策略包括:通过无缝排列 PTFE/PA/电极,在滑块上使用多单元结构优化空间,实现空间利用最大化;通过采用 PTFE、PA 和聚氨酯泡沫作为三电层,并在聚氨酯泡沫上自发引入 PTFE 粉末,选择三元介电材料,实现更高的三电化效应和表面润滑性;以及通过底部电极设计,在滑块上收集电荷收集电极(CCE)未到达的电荷,形成双直流输出。因此,TDD-TENG 的平均功率密度达到 18.37 W m-2,是滑动模式直流-TENG 中最高的。此外,旋转式 TDD-TENG 的输出电荷密度在每分钟 5 转的超低速下达到了 7.3 mC m-2。这项工作从结构设计和材料改性方面为直流-TENG 提供了一种提高输出功率的新方法。
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来源期刊
Chemical Reviews
Chemical Reviews 化学-化学综合
CiteScore
106.00
自引率
1.10%
发文量
278
审稿时长
4.3 months
期刊介绍: Chemical Reviews is a highly regarded and highest-ranked journal covering the general topic of chemistry. Its mission is to provide comprehensive, authoritative, critical, and readable reviews of important recent research in organic, inorganic, physical, analytical, theoretical, and biological chemistry. Since 1985, Chemical Reviews has also published periodic thematic issues that focus on a single theme or direction of emerging research.
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