Development of Polyoxometalate-loaded MOF for Heterogeneous Catalysis and Enhanced Dye Adsorption

Abstract

The study focuses here on the enhancement of MIL-117 functionality by incorporating well-known polyoxometalate (POM); tetrabutylammonium octamolybdate [(n-C4H9)4N]4[Mo8O26]. Using an encapsulation method with conventional heating, Mo8O264- anions were first time successfully integrated into the MIL-117 tubular channels (Mo8O26@MIL-117). Comprehensive characterization of the material through FTIR, XRD, BET, FE-SEM, EDX, and XPS confirmed the uniform distribution of Mo8O264- within MIL-117 without compromising its structural integrity. The Mo8O26@MIL-117 composite demonstrates exceptional catalytic performance in oxidative C-N bond formation and Paal-Knorr pyrrole synthesis, achieving high yields under optimized conditions with diverse amine substrates. Characterization and stability assessments confirm Mo8O26@MIL-117 as a robust and recyclable catalyst, maintaining structural integrity and catalytic activity over multiple cycles, highlighting its potential for sustainable applications in synthetic chemistry. The composite material was also evaluated for its efficacy in dye removal, specifically targeting Methylene blue (MB) and Rhodamine B (RHB) from aqueous solutions. Mo8O26@MIL-117 exhibited superior adsorption capacity for MB compared to MIL-117 alone, demonstrating high efficiency even at elevated concentrations. The composite showed improved selectivity towards MB over RHB, highlighting its potential for selective dye removal in wastewater treatment applications.