{"title":"Atomic Force Microscopy Analysis of Velocity Dependent Adhesive Viscoelastic Contact","authors":"Nobuhito Onozuka, Ken Nakajima","doi":"10.1021/acs.langmuir.4c03370","DOIUrl":null,"url":null,"abstract":"Adhesive contact phenomena play a crucial role in various scientific and engineering fields. However, considering viscoelasticity, which is essential for understanding practical applications involving soft materials like polymers, makes analysis challenging. Traditional elastic contact models such as the Johnson–Kendall–Roberts and Maugis–Dugdale models often fail to account for viscoelastic behavior. In this study, rate-dependent viscoelastic adhesive contacts were analyzed using atomic force microscopy force–distance curve measurements, comparing the elastic models with the viscoelastic model proposed by Barthel. The force curve analysis, conducted with the Barthel model for the first time, reveals that viscoelastic behaviors inside the contact area and the interaction zone both affect the contact state. These viscoelastic behaviors result in phenomena specific to viscoelastic contact, such as the “stick region” and the apparent work of adhesion. The Barthel model successfully captures the rate dependence of the contact situation, promoting a comprehensive understanding of viscoelastic adhesive contact phenomena.","PeriodicalId":50,"journal":{"name":"Langmuir","volume":null,"pages":null},"PeriodicalIF":3.7000,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Langmuir","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.langmuir.4c03370","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Adhesive contact phenomena play a crucial role in various scientific and engineering fields. However, considering viscoelasticity, which is essential for understanding practical applications involving soft materials like polymers, makes analysis challenging. Traditional elastic contact models such as the Johnson–Kendall–Roberts and Maugis–Dugdale models often fail to account for viscoelastic behavior. In this study, rate-dependent viscoelastic adhesive contacts were analyzed using atomic force microscopy force–distance curve measurements, comparing the elastic models with the viscoelastic model proposed by Barthel. The force curve analysis, conducted with the Barthel model for the first time, reveals that viscoelastic behaviors inside the contact area and the interaction zone both affect the contact state. These viscoelastic behaviors result in phenomena specific to viscoelastic contact, such as the “stick region” and the apparent work of adhesion. The Barthel model successfully captures the rate dependence of the contact situation, promoting a comprehensive understanding of viscoelastic adhesive contact phenomena.
期刊介绍:
Langmuir is an interdisciplinary journal publishing articles in the following subject categories:
Colloids: surfactants and self-assembly, dispersions, emulsions, foams
Interfaces: adsorption, reactions, films, forces
Biological Interfaces: biocolloids, biomolecular and biomimetic materials
Materials: nano- and mesostructured materials, polymers, gels, liquid crystals
Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry
Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals
However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do?
Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*.
This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).