Competitive influence of interface effect, scale effect and mixed salt ratio on thermal conductivity of mesoporous complex nitrate

Abstract

The rising prominence of energy security and climate change issues necessitates the advancement of sustainable energy development and energy storage technologies. Enhancing the capabilities of mesoporous composite phase change materials (CPCMs) has gained considerable research interest. CPCM’s heat storage and release performance is largely determined by its thermal conductivity. While the existing literature has documented the individual effects of the composition ratio of mixed molten salts, scale effects, and interfacial effects on thermal conductivity, no studies have been found that investigate the competitive interplay among these three factors with respect to their impact on thermal conductivity. This study aims to gain a deeper insight into the thermal conductivity changes of CPCM consisting of mixed molten salts as the phase change material (PCM) and mesoporous skeleton. A combination of molecular dynamics simulations and experimental investigations was employed to explore how interface effects, scale effects, and the proportion of mixed salts contribute to the thermal conductivity of CPCM. The findings indicate that augmented thermal conductivity, resulting from interface effects, supersedes the diminishing effects of interionic interactions. Compared to mixed salt ratios, interface effects primarily result in variations in the thermal conductivity of CPCM. The thermal conductivity of mixed nitrates escalates alongside scale increases. In the 3–4 nm range, the scale effect and mixed nitrate proportions do not notably compete in terms of influence on thermal conductivity, interface effects are more profound than scale effects. In the 4–9.5 nm range, the scale effect is more profound than mixed nitrate ratios. If the skeleton transitions from SiO₂ to Al₂O₃, the impact of the interface effect on thermal conductivity is greater influential than the scale effect. While transitioning the interface from Al₂O₃ to ceramic, the effect of the interface is less than or equal to that of the scale effect on the thermal conductivity.