Investigation of corrosion and electrical resistance in laser welded Al-Cu joints for EV batteries

IF 8.9 2区 工程技术 Q1 ENERGY & FUELS
Sunil Sinhmar , Saikat Mandal , Vijay Kumar Yadav , K. Mondal
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Abstract

This study investigates the correlation among the microstructure, electrochemical, and electrical properties of laser-welded AlCu joints used in battery applications. Aluminium and copper thin sheets were laser welded at three power inputs (2000 W, 2100 W, and 2200 W), and joints were evaluated for their macro- and microstructural features, corrosion behaviour, electrical resistance, and temperature rise during current supply. Results indicated that higher power inputs led to deeper weld penetration and increased intermetallic formation, impacting corrosion resistance and electrical characteristics. Electrochemical impedance spectroscopy (EIS), immersion, and Tafel tests confirmed that joints welded at 2200 W exhibited superior corrosion resistance than others, and this was attributed to a uniformly mixed AlCu region. The electric characteristics of the joints were assessed by supplying electric currents of 100 A, 150 A, and 200 A. In comparison to a weld joint developed at 2000 W, the electrical resistance of weld joints developed at 2200 W increased by 44.5 %, 37.87 %, and 39.31 % at 100 A, 150 A, and 200 A current supplies, respectively. Electrical resistance measurements revealed a direct correlation with weld quality and temperature rise, with implications on battery performance. These findings underscore the critical role of joint quality in optimizing battery performance.
电动汽车电池铝铜激光焊接接头的腐蚀和电阻研究
本研究探讨了电池应用中激光焊接铝铜接头的微观结构、电化学和电气性能之间的相关性。在三种功率输入(2000 瓦、2100 瓦和 2200 瓦)下对铝和铜薄板进行了激光焊接,并对接头的宏观和微观结构特征、腐蚀行为、电阻和电流供应期间的温升进行了评估。结果表明,输入功率越大,焊接渗透越深,金属间化合物形成越多,从而影响耐腐蚀性和电气特性。电化学阻抗光谱 (EIS)、浸入和塔菲尔测试证实,在 2200 W 下焊接的焊点比其他焊点具有更高的耐腐蚀性,这归因于铝铜区域的均匀混合。通过提供 100 A、150 A 和 200 A 的电流对焊点的电气特性进行了评估。与在 2000 W 条件下形成的焊点相比,在 2200 W 条件下形成的焊点在 100 A、150 A 和 200 A 电流供应下的电阻分别增加了 44.5 %、37.87 % 和 39.31 %。电阻测量结果表明,焊接质量和温升直接相关,对电池性能有影响。这些发现强调了焊接质量在优化电池性能方面的关键作用。
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来源期刊
Journal of energy storage
Journal of energy storage Energy-Renewable Energy, Sustainability and the Environment
CiteScore
11.80
自引率
24.50%
发文量
2262
审稿时长
69 days
期刊介绍: Journal of energy storage focusses on all aspects of energy storage, in particular systems integration, electric grid integration, modelling and analysis, novel energy storage technologies, sizing and management strategies, business models for operation of storage systems and energy storage developments worldwide.
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