Assessment of cerium adsorption potential of phosphoric acid activated biochar in aqueous system: Modelling and mechanistic insights

Abstract

Cerium pollution in waterbodies by improper industrial waste disposal is a major concern due to its detrimental impacts on the environment. Therefore, treatment of cerium-contaminated water is inevitable. Hence, this study is focused on the remediation of cerium pollution using phosphoric acid-activated biochar (PPMB) as an adsorbent, synthesized upon pyrolytic activation of palmyra palm male flower-based pristine biochar (PMFB) with H₃PO₄ at 500 °C. The physico-chemical surface properties of PMFB and PPMB were evaluated through various microscopic and spectroscopic analyses. The key parameters such as biochar dosage, pH, temperature, contact time and initial cerium concentration were optimized as 0.5 g/L, 5.0, 303 K, 180 min and 50 mg/L respectively via batch adsorption. Pseudo-second order kinetic and Toth isotherm are the best-fitted models. The thermodynamic parameters including ΔG^◦ (−30.4707 ± 0.7618 kJ/mol at 303 K), ΔH^◦ (16.1499 ± 0.78 kJ/mol), and ΔS^◦ (153.617 ± 3.8404 J/mol/K) conveying that cerium adsorption onto PPMB was spontaneous, endothermic, and highly disordered at PPMB-bulk adsorption medium interface. Precipitation, electrostatic attraction, and surface complexation are predicted to be the predominant mechanisms for the chosen PPMB-cerium adsorption system. Moreover, cerium phytotoxicity on Vigna radiata explains the real-time applicability and feasibility of cerium adsorption using PPMB. Thus, the key findings of this study specified that the higher adsorption capacity of PPMB (141.3484 ± 6.9856 mg/g) contributed by the incorporated phosphate groups, predominant mesoporosity, SSA_BET of 230.559 m²/g and anionic surface at a wider pH range (pH>3.08) make PPMB as efficient, economically feasible and environmentally friendly adsorbent for cerium adsorption in aqueous system.