{"title":"Exploring the boundaries of covalency","authors":"Zuping Xiong, Haoke Zhang","doi":"10.1038/s41570-024-00672-5","DOIUrl":null,"url":null,"abstract":"One electron σ-bonds were first proposed in 1931 but most discussion since then has been at a theoretical level. The first experimentally observed single-electron C–C bond both advances our fundamental understanding of bonding and provides the basis of an approach to creating a new class of molecules.","PeriodicalId":18849,"journal":{"name":"Nature reviews. Chemistry","volume":null,"pages":null},"PeriodicalIF":38.1000,"publicationDate":"2024-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nature reviews. Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1038/s41570-024-00672-5","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
One electron σ-bonds were first proposed in 1931 but most discussion since then has been at a theoretical level. The first experimentally observed single-electron C–C bond both advances our fundamental understanding of bonding and provides the basis of an approach to creating a new class of molecules.
期刊介绍:
Nature Reviews Chemistry is an online-only journal that publishes Reviews, Perspectives, and Comments on various disciplines within chemistry. The Reviews aim to offer balanced and objective analyses of selected topics, providing clear descriptions of relevant scientific literature. The content is designed to be accessible to recent graduates in any chemistry-related discipline while also offering insights for principal investigators and industry-based research scientists. Additionally, Reviews should provide the authors' perspectives on future directions and opinions regarding the major challenges faced by researchers in the field.