Bottlebrush polymers via ring-opening metathesis polymerization (ROMP): Synthesis, properties and applications

IF 5.8 2区 化学 Q1 POLYMER SCIENCE
Smruti Rekha Rout , Gowtham Kenguva , Shaaba Mansuri , Manu KR , Rambabu Dandela , Nabendu B. Pramanik
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引用次数: 0

Abstract

Bottlebrush polymers (BBPs) are a class of branch or graft macromolecules with polymeric side chains attached to linear backbone leading to cylindrical or worm like structures. Due to their unique architecture of polymers with long and densely grafted side chains, BBPs have attracted notable numbers of novel and unique properties useful for various applications from tissue engineering to photonics. Their unique structures characterized by densely-grafted side chains, allows for precise control of their properties and reduces issues with entanglements. This review delineates the recent advances in the synthesis of BBPs via living Ring-Opening Metathesis Polymerization (ROMP) and their properties, applications, highlighting the challenges and solutions in controlling their chemical structures, compositions and uses. Notably, the development of ROMP has transformed the polymer synthesis, specially the synthesis of bottlebrush polymers. ROMP is very powerful technique for achieving very high conversion of macromonomer for a range of concentrations and molecular weights of macromonomer leading to formation of BBPs with systemically varying backbone and side-chain lengths. The combination of BBPs’ versatility with ROMP’s precision in controlling the polymer’s size, shape, and functionality offers significant advantages in materials synthesis. By integrating these approaches, researchers can create customized bottlebrush polymeric materials with tailored properties, enhancing advancements in nanotechnology, energy storage and biomedical engineering. To the best of our knowledge there is no review reported on the synthesis of BBPs via ROMP.

Abstract Image

通过开环偏聚聚合(ROMP)制备的瓶坯聚合物:合成、性能和应用
Bottlebrush 聚合物(BBPs)是一类分支或接枝高分子,其聚合物侧链附着在线性骨架上,形成圆柱形或蠕虫状结构。由于其独特的聚合物结构具有长而密集的接枝侧链,BBPs 具有大量新颖独特的特性,可用于组织工程和光子学等各种应用领域。以密集接枝侧链为特征的独特结构可以精确控制其特性,并减少缠结问题。本综述介绍了通过活环开环元合成聚合法(ROMP)合成 BBPs 的最新进展及其特性和应用,重点介绍了在控制其化学结构、组成和用途方面所面临的挑战和解决方案。值得注意的是,ROMP 的发展改变了聚合物合成,特别是瓶丛聚合物的合成。ROMP 是一种非常强大的技术,可在各种浓度和分子量的大单体中实现非常高的大单体转化率,从而形成具有系统性不同骨架和侧链长度的 BBPs。BBPs 的多功能性与 ROMP 在控制聚合物大小、形状和功能方面的精确性相结合,为材料合成提供了显著优势。通过整合这些方法,研究人员可以制造出具有定制特性的瓶绒聚合物材料,从而推动纳米技术、能量存储和生物医学工程的发展。据我们所知,目前还没有关于通过 ROMP 合成 BBPs 的综述。
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来源期刊
European Polymer Journal
European Polymer Journal 化学-高分子科学
CiteScore
9.90
自引率
10.00%
发文量
691
审稿时长
23 days
期刊介绍: European Polymer Journal is dedicated to publishing work on fundamental and applied polymer chemistry and macromolecular materials. The journal covers all aspects of polymer synthesis, including polymerization mechanisms and chemical functional transformations, with a focus on novel polymers and the relationships between molecular structure and polymer properties. In addition, we welcome submissions on bio-based or renewable polymers, stimuli-responsive systems and polymer bio-hybrids. European Polymer Journal also publishes research on the biomedical application of polymers, including drug delivery and regenerative medicine. The main scope is covered but not limited to the following core research areas: Polymer synthesis and functionalization • Novel synthetic routes for polymerization, functional modification, controlled/living polymerization and precision polymers. Stimuli-responsive polymers • Including shape memory and self-healing polymers. Supramolecular polymers and self-assembly • Molecular recognition and higher order polymer structures. Renewable and sustainable polymers • Bio-based, biodegradable and anti-microbial polymers and polymeric bio-nanocomposites. Polymers at interfaces and surfaces • Chemistry and engineering of surfaces with biological relevance, including patterning, antifouling polymers and polymers for membrane applications. Biomedical applications and nanomedicine • Polymers for regenerative medicine, drug delivery molecular release and gene therapy The scope of European Polymer Journal no longer includes Polymer Physics.
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