Smruti Rekha Rout , Gowtham Kenguva , Shaaba Mansuri , Manu KR , Rambabu Dandela , Nabendu B. Pramanik
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引用次数: 0
Abstract
Bottlebrush polymers (BBPs) are a class of branch or graft macromolecules with polymeric side chains attached to linear backbone leading to cylindrical or worm like structures. Due to their unique architecture of polymers with long and densely grafted side chains, BBPs have attracted notable numbers of novel and unique properties useful for various applications from tissue engineering to photonics. Their unique structures characterized by densely-grafted side chains, allows for precise control of their properties and reduces issues with entanglements. This review delineates the recent advances in the synthesis of BBPs via living Ring-Opening Metathesis Polymerization (ROMP) and their properties, applications, highlighting the challenges and solutions in controlling their chemical structures, compositions and uses. Notably, the development of ROMP has transformed the polymer synthesis, specially the synthesis of bottlebrush polymers. ROMP is very powerful technique for achieving very high conversion of macromonomer for a range of concentrations and molecular weights of macromonomer leading to formation of BBPs with systemically varying backbone and side-chain lengths. The combination of BBPs’ versatility with ROMP’s precision in controlling the polymer’s size, shape, and functionality offers significant advantages in materials synthesis. By integrating these approaches, researchers can create customized bottlebrush polymeric materials with tailored properties, enhancing advancements in nanotechnology, energy storage and biomedical engineering. To the best of our knowledge there is no review reported on the synthesis of BBPs via ROMP.
期刊介绍:
European Polymer Journal is dedicated to publishing work on fundamental and applied polymer chemistry and macromolecular materials. The journal covers all aspects of polymer synthesis, including polymerization mechanisms and chemical functional transformations, with a focus on novel polymers and the relationships between molecular structure and polymer properties. In addition, we welcome submissions on bio-based or renewable polymers, stimuli-responsive systems and polymer bio-hybrids. European Polymer Journal also publishes research on the biomedical application of polymers, including drug delivery and regenerative medicine. The main scope is covered but not limited to the following core research areas:
Polymer synthesis and functionalization
• Novel synthetic routes for polymerization, functional modification, controlled/living polymerization and precision polymers.
Stimuli-responsive polymers
• Including shape memory and self-healing polymers.
Supramolecular polymers and self-assembly
• Molecular recognition and higher order polymer structures.
Renewable and sustainable polymers
• Bio-based, biodegradable and anti-microbial polymers and polymeric bio-nanocomposites.
Polymers at interfaces and surfaces
• Chemistry and engineering of surfaces with biological relevance, including patterning, antifouling polymers and polymers for membrane applications.
Biomedical applications and nanomedicine
• Polymers for regenerative medicine, drug delivery molecular release and gene therapy
The scope of European Polymer Journal no longer includes Polymer Physics.