Granulometric and Geochemical Distribution of Arsenic in a Mining Environmental Liability in a Semi-arid Area.

Abstract

This study focuses on the "El Lavadero" tailings deposit, a mining environmental liability (MEL) located near the town of San Felipe de Jesús, Sonora, in northwest Mexico. The objective was to determine the total arsenic (As) content, its granulometric and geochemical distribution, as well as its mobilization capacity and bioavailability. The results from oxidized and unoxidized tailings showed low potential of hydrogen (pH) values (2.4-5.7) and high concentrations of total arsenic (8235-36,004 mg kg^-1), predominantly in the finer granulometric fractions (< 0.05 mm). Arsenic also prevails in the finest fraction of agricultural soil (> 2 mm). These fine particles could present adverse environmental effects due to their potential to be transported by leaching and water suspension. In contrast, arsenic in the effluent sediments is primarily found in the coarser fraction (> 2 mm). A significant proportion of arsenic in the tailings (5-40%) was found in the non-residual geochemical fractions (I + II + III) (1106-7675 mg kg^-1), indicating potential for mobilization and bioavailability. Depending on environmental conditions (redox potential and pH), arsenic can redissolve and exhibit high mobility in abiotic media, which may ultimately impact the environment and human health. Therefore, it is crucial to rehabilitate the "El Lavadero" MEL to prevent further environmental damage. This study provides useful information to understand some phenomena in other global mining environmental liabilities, such as mobilization and bioavailability of arsenic and its possible impact on the surrounding environment and biota, contributing to the worldwide research of ecosystems polluted by mining activity, especially in arid and semi-arid climates.