Tb–Co–In system at 870 K and magnetic ordering of Tb2CoIn8, Tb23Co7In20, Tb26Co5In12 and Tb6Co2In

IF 3.2 3区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR
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引用次数: 0

Abstract

The Tb–Co–In system at 870 K has been investigated by X-ray powder diffraction and microprobe elemental analyses. The existence of the known compounds TbCo2In (PrCo2Ga-type), Tb2CoIn8 (Ho2CoGa8-type), Tb11Co4In9 (Nd11Pd4In9-type), Tb23Co7In20 (Er23Co6.7In20.3-type), Tb6Co2In (Ho6Co2Ga-type) and Tb14Co3In3 (Gd14Co3In2.7-type) has been confirmed and novel Sm26Co11Ga6-type Tb26Co56In12-11 (space group P4/mbm, N 127, tP86), ∼Tb18Co67In15, ∼Tb5Co3In2 (unknown structure) and qusibinary PuNi3-type Tb1-0.74Co3In0-0.26 have been detected in the Tb–Co–In system at 870 K. The appreciable solubility of other binaries was no observed in the Tb–Co–In system.
The Ho2CoGa8-type Tb2CoIn8 shows antiferromagnetic ordering at TN = 32 K with field-sensitive paramagnetic state and the Sm26Co11Ga6-type Tb26Co5In12 exhibits the Curie temperature (TC) at 72 K. The Er23Co6.7In20.3-type Tb23Co7In20 ferromagnet with TC = 56 K and Tm ∼28 K in a field of 10 kOe and it shows hard magnetic properties at low temperatures. The Ho6Co2Ga-type Tb6Co2In shows field-sensitive ferro-antiferromagnetic ordering below 75 K.
870 K 时的锑-钴-铟体系以及 Tb2CoIn8、Tb23Co7In20、Tb26Co5In12 和 Tb6Co2In 的磁有序性
通过 X 射线粉末衍射和微探针元素分析,研究了 870 K 下的 Tb-Co-In 系统。已知化合物 TbCo2In(PrCo2Ga 型)、Tb2CoIn8(Ho2CoGa8 型)、Tb11Co4In9(Nd11Pd4In9 型)、Tb23Co7In20(Er23Co6.7In20.3 型)、Tb6Co2In(Ho6Co2Ga 型)和 Tb14Co3In3(Gd14Co3In2.在 870 K 时,Tb-Co-In 体系中还发现了新的 Sm26Co11Ga6 型 Tb26Co5-6In12-11(空间群 P4/mbm,N 127,tP86)、∼Tb18Co67In15、∼Tb5Co3In2(未知结构)和 Qusibinary PuNi3 型 Tb1-0.74Co3In0-0.26 。Ho2CoGa8 型 Tb2CoIn8 在 TN = 32 K 时显示出反铁磁有序和场敏顺磁态,Sm26Co11Ga6 型 Tb26Co5In12 在 72 K 时显示出居里温度(TC)。Er23Co6.7In20.3 型 Tb23Co7In20 铁磁体在 10 kOe 磁场中的 TC = 56 K 和 Tm ∼ 28 K,在低温下显示出硬磁性。Ho6Co2Ga 型 Tb6Co2In 在 75 K 以下显示出场敏感铁反铁磁有序性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Journal of Solid State Chemistry
Journal of Solid State Chemistry 化学-无机化学与核化学
CiteScore
6.00
自引率
9.10%
发文量
848
审稿时长
25 days
期刊介绍: Covering major developments in the field of solid state chemistry and related areas such as ceramics and amorphous materials, the Journal of Solid State Chemistry features studies of chemical, structural, thermodynamic, electronic, magnetic, and optical properties and processes in solids.
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