Experimental study of ammonia energy ratio on combustion and emissions from ammonia-gasoline dual-fuel engine at various load conditions

Abstract

Achieving carbon neutrality necessitates the adoption of zero-carbon fuels in engine applications, with ammonia emerging as an up-and-coming candidate due to its favorable safety profile and advantages in storage and transportation. This study experimentally investigated the feasibility of an ammonia-gasoline dual-fuel (AGDF) engine to achieve comparable power output and satisfactory carbon reduction without changing the main structural parameters of the engine. A four-cylinder, naturally aspirated, spark ignition engine was used to investigate the impact of ammonia energy ratio (AER), engine base torque and engine speed on the engine performance, combustion evolution and emission characteristics. The findings reveal that the brake thermal efficiency (BTE) in AGDF mode is lower than in gasoline-only mode, primarily due to the reduced combustion activity. However, this efficiency decline becomes noticeable only when the AER exceeds 15 %. Additionally, at high AERs and high engine base torques, the delayed effect of ammonia fuel on the main combustion period results in a double-peak pattern, which limits the energy output but presents opportunities for phase optimization. The study also examined three incomplete combustion emissions, each exhibiting distinct behaviors. Except for ammonia slip, adding ammonia fuel does not significantly affect carbon monoxide (CO) and unburned hydrocarbons (UHC) emissions, particularly at AERs below 25 %. Nevertheless, nitrogen oxide (NOx) emissions under AGDF combustion are significantly higher than under gasoline alone in most instances. Crucially, the study demonstrates the carbon reduction potential of ammonia fuel across different engine loads, with a maximum carbon dioxide (CO₂) reduction of 46.8 % at a 35 % AER. It is anticipated that further optimization of the combustion phase will improve the capability for carbon reduction.