Composite electroforming of precision Ni-P-PTFE mold inserts with low internal stress and self-lubricating properties

IF 5.3 2区 材料科学 Q1 MATERIALS SCIENCE, COATINGS & FILMS
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Abstract

An electrolyte solution incorporating sodium saccharin and an alkynyl compound was provided to electroform Ni-P-PTFE mold inserts with both low internal stress and good self-lubricating properties. The results showed that with 5 g·L−1 sodium saccharin and 1 mL·L−1 alkynyl compound, the internal stress reached a minimum of −114 MPa, an 82 % reduction from the −646 MPa observed without additives. The presence of sodium saccharin and alkynyl compound in the electrolyte solution reduced the hydrogen evolution reaction current from 15.2 to 12.9 mA at the operating cathode potential of −1 V and decreased the RTC(111) from 100 % to 90 %. The reduction of internal stress in the electrodeposited Ni-P-PTFE composites was attributed to the decreased hydrogenation strain, diminished Ni (111) texture intensity, and the partial incorporation of alkynyl compound reaction products into the deposits, which weakened the connections between crystallites. Finally, 5 g·L−1 sodium saccharin and 1 mL·L−1 alkynyl compound was applied to electroform Ni-P-PTFE mold insert with micro features. Only slightly pile-up defects at the corner of grooves were observed on the polymer chips demolded from Ni-P-PTFE mold insert, demonstrating its good self-lubricating property.

Abstract Image

复合电铸具有低内应力和自润滑特性的精密 Ni-P-PTFE 模具镶件
提供了一种含有糖精钠和炔基化合物的电解质溶液,用于电铸具有低内应力和良好自润滑性能的 Ni-P-PTFE 模具镶件。结果表明,在使用 5 g-L-1 糖精钠和 1 mL-L-1 烷基化合物的情况下,内应力最低达到 -114 MPa,比不使用添加剂时的 -646 MPa 降低了 82%。电解质溶液中糖精钠和炔基化合物的存在使工作阴极电位为 -1 V 时的氢演化反应电流从 15.2 mA 降至 12.9 mA,RTC(111)从 100 % 降至 90 %。电沉积 Ni-P-PTFE 复合材料内应力的降低归因于氢化应变的降低、Ni(111)纹理强度的减弱以及沉积物中部分炔基化合物反应产物的掺入,这削弱了晶粒之间的连接。最后,将 5 g-L-1 糖精钠和 1 mL-L-1 烷基化合物用于电铸具有微特征的 Ni-P-PTFE 模具镶件。从 Ni-P-PTFE 模芯脱模的聚合物芯片上仅在凹槽角落处观察到轻微的堆积缺陷,表明其具有良好的自润滑性能。
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来源期刊
Surface & Coatings Technology
Surface & Coatings Technology 工程技术-材料科学:膜
CiteScore
10.00
自引率
11.10%
发文量
921
审稿时长
19 days
期刊介绍: Surface and Coatings Technology is an international archival journal publishing scientific papers on significant developments in surface and interface engineering to modify and improve the surface properties of materials for protection in demanding contact conditions or aggressive environments, or for enhanced functional performance. Contributions range from original scientific articles concerned with fundamental and applied aspects of research or direct applications of metallic, inorganic, organic and composite coatings, to invited reviews of current technology in specific areas. Papers submitted to this journal are expected to be in line with the following aspects in processes, and properties/performance: A. Processes: Physical and chemical vapour deposition techniques, thermal and plasma spraying, surface modification by directed energy techniques such as ion, electron and laser beams, thermo-chemical treatment, wet chemical and electrochemical processes such as plating, sol-gel coating, anodization, plasma electrolytic oxidation, etc., but excluding painting. B. Properties/performance: friction performance, wear resistance (e.g., abrasion, erosion, fretting, etc), corrosion and oxidation resistance, thermal protection, diffusion resistance, hydrophilicity/hydrophobicity, and properties relevant to smart materials behaviour and enhanced multifunctional performance for environmental, energy and medical applications, but excluding device aspects.
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