Effect of laser remelting on the microstructures and properties of NiCoCrAlY-based coatings prepared by high-speed air fuel supersonic flame (HVAF)

IF 5.3 2区 材料科学 Q1 MATERIALS SCIENCE, COATINGS & FILMS
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Abstract

In order to improve the oxidation resistance of the coating, laser remelting technology was used to remelt the HVAF multi-component modified coating. The influence of laser remelting technology on the phase state, microstructure characteristics, and isothermal oxidation behavior of coatings was studied. The experimental results indicate that a coating with complete morphology and no defects was obtained on the surface. There is a significant amount of metallurgical bonding and partial mechanical interlocking between the remelted layer and the substrate. The remelted layer is mainly composed of β-NiAl phase, accompanied by a small amount of γ′ phase and oxide phase. The microhardness test results show that the average hardness of the remelted layer is 1.1–1.42 times that of the prepared coating, and the bonding strength has increased by 23 %. After 100 h of high-temperature oxidation, the oxidation rate of the 4N3T4H remelted layer is the lowest, at 1.5 × 10−15 cm2/s, which is one order of magnitude lower than that of the as-sprayed coating. This is because after laser remelting, the remelted layer has the inherent hysteresis diffusion effect of HEA, which can improve the high-temperature oxidation resistance of the remelted layer and basically eliminate many pores and cracks contained in the HVAF coating. The coating density is significantly increased, which is conducive to hindering the diffusion of oxygen. Meanwhile, the oxide of HVAF coating mainly accumulates at pores and cracks, and there is no or late formation of uniform and dense oxide film on the surface. The surface of the remelted coating after oxidation forms a relatively uniform and dense oxide film, providing more effective protection for the substrate.
激光重熔对高速空气燃料超音速火焰 (HVAF) 制备的镍钴铬铝基合金涂层微观结构和性能的影响
为了提高涂层的抗氧化性,采用激光重熔技术重熔了 HVAF 多组分改性涂层。研究了激光重熔技术对涂层相态、微观结构特征和等温氧化行为的影响。实验结果表明,涂层表面形态完整,无缺陷。重熔层和基体之间存在大量的冶金结合和部分机械互锁。重熔层主要由 β-NiAl 相组成,并伴有少量的 γ′ 相和氧化物相。显微硬度测试结果表明,重熔层的平均硬度是制备涂层的 1.1-1.42 倍,结合强度提高了 23%。经过 100 小时的高温氧化后,4N3T4H 重熔层的氧化速率最低,为 1.5 × 10-15 cm2/s,比原样喷涂涂层的氧化速率低一个数量级。这是因为激光重熔后,重熔层具有 HEA 固有的滞后扩散效应,可以提高重熔层的高温抗氧化性,从根本上消除 HVAF 涂层中含有的许多气孔和裂纹。涂层密度明显增加,有利于阻碍氧气的扩散。同时,HVAF 涂层的氧化物主要聚集在孔隙和裂缝处,表面没有形成或较晚形成均匀致密的氧化膜。氧化后的重熔涂层表面会形成相对均匀致密的氧化膜,为基材提供更有效的保护。
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来源期刊
Surface & Coatings Technology
Surface & Coatings Technology 工程技术-材料科学:膜
CiteScore
10.00
自引率
11.10%
发文量
921
审稿时长
19 days
期刊介绍: Surface and Coatings Technology is an international archival journal publishing scientific papers on significant developments in surface and interface engineering to modify and improve the surface properties of materials for protection in demanding contact conditions or aggressive environments, or for enhanced functional performance. Contributions range from original scientific articles concerned with fundamental and applied aspects of research or direct applications of metallic, inorganic, organic and composite coatings, to invited reviews of current technology in specific areas. Papers submitted to this journal are expected to be in line with the following aspects in processes, and properties/performance: A. Processes: Physical and chemical vapour deposition techniques, thermal and plasma spraying, surface modification by directed energy techniques such as ion, electron and laser beams, thermo-chemical treatment, wet chemical and electrochemical processes such as plating, sol-gel coating, anodization, plasma electrolytic oxidation, etc., but excluding painting. B. Properties/performance: friction performance, wear resistance (e.g., abrasion, erosion, fretting, etc), corrosion and oxidation resistance, thermal protection, diffusion resistance, hydrophilicity/hydrophobicity, and properties relevant to smart materials behaviour and enhanced multifunctional performance for environmental, energy and medical applications, but excluding device aspects.
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