{"title":"Surfactant-modified zein nanoparticles adsorbents for ultrafast and efficient removal of Cr(VI).","authors":"Qing Shen, Xiaomeng Xu, Xiaojing Liang, Cong Tang, Xiaoping Bai, Shijun Shao, Qing Liang, Shuqing Dong","doi":"10.1016/j.envres.2024.120284","DOIUrl":null,"url":null,"abstract":"<p><p>The adsorption and removal of heavy metal ions Cr(VI) is of great significance for human health and ecological environment. Here, a ultrafast and high efficient adsorbent for Cr(VI) was developed based on cetyltrimethylammonium bromide (CTAB)-modified zein nanoparticles (C-ZNPs). In comparison to pristine zein nanoparticles (ZNPs) (11.199 m<sup>2</sup>·g<sup>-1</sup>), the surfactant-modified C-ZNPs exhibited larger specific surface area (17.002 m<sup>2</sup>·g<sup>-1</sup>). Moreover, C-ZNPs had superior dispersion and more positive charge distribution, which contributed to the improvement for adsorption performance. The results showed that the saturated adsorption of Cr(VI) was reached up to 192.27 mg/g using the C-ZNPs nanosorbent at T = 298 K, pH = 4, t = 10s, and C<sub>0</sub> = 125 mg/L. The removal rate was significantly faster than that reported natural polymer-based adsorbents. The experimental values were followed Freundich isothermal model and pseudo-second-order kinetic model, indicating that the adsorption occurred primarily through a multimolecular layer adsorption process, with a strong emphasis on chemisorption. Mechanistic investigations further revealed that the adsorption of Cr(VI) onto C-ZNPs was mediated by various interactions, including electrostatic attraction, complexation, and ion exchange. These findings provide insights into the efficient removal of Cr(VI) by C-ZNPs and suggest potential applications in water treatment and environmental remediation.</p>","PeriodicalId":312,"journal":{"name":"Environmental Research","volume":null,"pages":null},"PeriodicalIF":7.7000,"publicationDate":"2024-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Research","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.1016/j.envres.2024.120284","RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 0
Abstract
The adsorption and removal of heavy metal ions Cr(VI) is of great significance for human health and ecological environment. Here, a ultrafast and high efficient adsorbent for Cr(VI) was developed based on cetyltrimethylammonium bromide (CTAB)-modified zein nanoparticles (C-ZNPs). In comparison to pristine zein nanoparticles (ZNPs) (11.199 m2·g-1), the surfactant-modified C-ZNPs exhibited larger specific surface area (17.002 m2·g-1). Moreover, C-ZNPs had superior dispersion and more positive charge distribution, which contributed to the improvement for adsorption performance. The results showed that the saturated adsorption of Cr(VI) was reached up to 192.27 mg/g using the C-ZNPs nanosorbent at T = 298 K, pH = 4, t = 10s, and C0 = 125 mg/L. The removal rate was significantly faster than that reported natural polymer-based adsorbents. The experimental values were followed Freundich isothermal model and pseudo-second-order kinetic model, indicating that the adsorption occurred primarily through a multimolecular layer adsorption process, with a strong emphasis on chemisorption. Mechanistic investigations further revealed that the adsorption of Cr(VI) onto C-ZNPs was mediated by various interactions, including electrostatic attraction, complexation, and ion exchange. These findings provide insights into the efficient removal of Cr(VI) by C-ZNPs and suggest potential applications in water treatment and environmental remediation.
期刊介绍:
The Environmental Research journal presents a broad range of interdisciplinary research, focused on addressing worldwide environmental concerns and featuring innovative findings. Our publication strives to explore relevant anthropogenic issues across various environmental sectors, showcasing practical applications in real-life settings.