Foam separation of radio-molybdenum oxyanions (99MoO42−) incorporated into Co(II)/Al(III) layered double hydroxide using anionic surfactant

IF 1.6 3区 工程技术 Q3 CHEMISTRY, INORGANIC & NUCLEAR
{"title":"Foam separation of radio-molybdenum oxyanions (99MoO42−) incorporated into Co(II)/Al(III) layered double hydroxide using anionic surfactant","authors":"","doi":"10.1016/j.apradiso.2024.111577","DOIUrl":null,"url":null,"abstract":"<div><div>Foam separation of radio-molybdenum oxyanions (<sup>99</sup>MoO<sub>4</sub><sup>2−</sup>) incorporated into in-situ formed Co(II)/Al(III) layered double hydroxide (LDH) particles was applied for recovery of these anionic species from aqueous solutions. The results showed that Co(II)/Al(III) molar ratios of 2 and 2.5 resulted into not only high recovery values for <sup>99</sup>MoO<sub>4</sub><sup>2−</sup> (R &gt; 0.97), but also high decontamination factor (DF = 33 and 36, respectively). Almost complete recovery was achieved for <sup>99</sup>MoO<sub>4</sub><sup>2−</sup> coprecipitated with Co(II)/Al(III) LDH in the pH range 9.9–10.5. Ageing time of 5 min was sufficient to completely coprecipitate the concerned anionic species. Sodium dodecyl sulfate (SDS) concentrations in the range 1.5 × 10<sup>−3</sup> - 3 × 10<sup>−3</sup> mol/L had the ability to efficiently form hydrophobic <sup>99</sup>MoO<sub>4</sub><sup>2-</sup>-Co(II)/Al(III)-LDH particles, where recovery values of about 0.96 were achieved with high DF values. The influence of the coexistence of different foreign anions (Cl<sup>−</sup>, NO<sub>3</sub><sup>−</sup>, HCO<sub>3</sub><sup>−</sup>, CO<sub>3</sub><sup>2−</sup> and SO<sub>4</sub><sup>2−</sup>) during coprecipitation process of <sup>99</sup>MoO<sub>4</sub><sup>2−</sup> and foam separation of the resultant particles was investigated. The suggested strategy in the present study was effectively applied for recovery of <sup>99</sup>MoO<sub>4</sub><sup>2−</sup> anions from ground water (R ≈ 0.98 and enrichment ratio (ER ≈ 7172) and radioactive process wastewater (R ≈ 0.96 and ER = 3887). Based on characterization of Co(II)/Al(III) LDH using Fourier transform infrared (FTIR) and X-ray diffraction (XRD) before and after foam separation process using SDS and the obtained data, the recovery mechanism of <sup>99</sup>MoO<sub>4</sub><sup>2−</sup> was proposed.</div></div>","PeriodicalId":8096,"journal":{"name":"Applied Radiation and Isotopes","volume":null,"pages":null},"PeriodicalIF":1.6000,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Radiation and Isotopes","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0969804324004056","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0

Abstract

Foam separation of radio-molybdenum oxyanions (99MoO42−) incorporated into in-situ formed Co(II)/Al(III) layered double hydroxide (LDH) particles was applied for recovery of these anionic species from aqueous solutions. The results showed that Co(II)/Al(III) molar ratios of 2 and 2.5 resulted into not only high recovery values for 99MoO42− (R > 0.97), but also high decontamination factor (DF = 33 and 36, respectively). Almost complete recovery was achieved for 99MoO42− coprecipitated with Co(II)/Al(III) LDH in the pH range 9.9–10.5. Ageing time of 5 min was sufficient to completely coprecipitate the concerned anionic species. Sodium dodecyl sulfate (SDS) concentrations in the range 1.5 × 10−3 - 3 × 10−3 mol/L had the ability to efficiently form hydrophobic 99MoO42--Co(II)/Al(III)-LDH particles, where recovery values of about 0.96 were achieved with high DF values. The influence of the coexistence of different foreign anions (Cl, NO3, HCO3, CO32− and SO42−) during coprecipitation process of 99MoO42− and foam separation of the resultant particles was investigated. The suggested strategy in the present study was effectively applied for recovery of 99MoO42− anions from ground water (R ≈ 0.98 and enrichment ratio (ER ≈ 7172) and radioactive process wastewater (R ≈ 0.96 and ER = 3887). Based on characterization of Co(II)/Al(III) LDH using Fourier transform infrared (FTIR) and X-ray diffraction (XRD) before and after foam separation process using SDS and the obtained data, the recovery mechanism of 99MoO42− was proposed.
使用阴离子表面活性剂对掺入 Co(II)/Al(III) 双层氢氧化物中的放射性钼氧阴离子 (99MoO42-) 进行泡沫分离。
采用泡沫分离法分离原位形成的 Co(II)/Al(III) 双层氢氧化物(LDH)颗粒中的放射性钼氧阴离子(99MoO42-),以从水溶液中回收这些阴离子物种。结果表明,Co(II)/Al(III) 摩尔比分别为 2 和 2.5 时,不仅 99MoO42- 的回收率高(R > 0.97),而且去污系数也高(DF = 33 和 36)。在 pH 值为 9.9-10.5 的范围内,99MoO42- 与 Co(II)/Al(III) LDH 共沉淀几乎实现了完全回收。5 分钟的老化时间足以完全共沉淀相关的阴离子物种。十二烷基硫酸钠(SDS)的浓度范围为 1.5 × 10-3 - 3 × 10-3 mol/L,能够有效地形成疏水性 99MoO42--Co(II)/Al(III)--LDH颗粒,其回收率约为 0.96,DF 值较高。研究了 99MoO42- 共沉淀过程中不同外来阴离子(Cl-、NO3-、HCO3-、CO32- 和 SO42-)共存的影响以及所得颗粒的泡沫分离。本研究建议的策略有效地用于从地下水(R ≈ 0.98,富集比 (ER ≈ 7172))和放射性工艺废水(R ≈ 0.96,ER = 3887)中回收 99MoO42- 阴离子。根据使用 SDS 进行泡沫分离前后 Co(II)/Al(III) LDH 的傅立叶变换红外光谱 (FTIR) 和 X 射线衍射 (XRD) 表征以及获得的数据,提出了 99MoO42- 的回收机制。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Applied Radiation and Isotopes
Applied Radiation and Isotopes 工程技术-核科学技术
CiteScore
3.00
自引率
12.50%
发文量
406
审稿时长
13.5 months
期刊介绍: Applied Radiation and Isotopes provides a high quality medium for the publication of substantial, original and scientific and technological papers on the development and peaceful application of nuclear, radiation and radionuclide techniques in chemistry, physics, biochemistry, biology, medicine, security, engineering and in the earth, planetary and environmental sciences, all including dosimetry. Nuclear techniques are defined in the broadest sense and both experimental and theoretical papers are welcome. They include the development and use of α- and β-particles, X-rays and γ-rays, neutrons and other nuclear particles and radiations from all sources, including radionuclides, synchrotron sources, cyclotrons and reactors and from the natural environment. The journal aims to publish papers with significance to an international audience, containing substantial novelty and scientific impact. The Editors reserve the rights to reject, with or without external review, papers that do not meet these criteria. Papers dealing with radiation processing, i.e., where radiation is used to bring about a biological, chemical or physical change in a material, should be directed to our sister journal Radiation Physics and Chemistry.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信