N. N. Bushuev, D. S. Zinin, G. K. Tatosyan, N. V. Sviridenkova
{"title":"Determination of Potassium, Neodymium, and Strontium in Solid Solutions in the KNd(SO4)2·H2O–SrSO4·0.5H2O System Using X-Ray Fluorescence Spectrometry","authors":"N. N. Bushuev, D. S. Zinin, G. K. Tatosyan, N. V. Sviridenkova","doi":"10.1134/S1061934824700977","DOIUrl":null,"url":null,"abstract":"<p>The composition of solid solutions in the KNd(SO<sub>4</sub>)<sub>2</sub>·H<sub>2</sub>O–SrSO<sub>4</sub>·0.5H<sub>2</sub>O system, synthesized from aqueous solutions of KCl, NdCl<sub>3</sub>, SrCl<sub>2</sub>, and H<sub>2</sub>SO<sub>4</sub>, was studied by X-ray fluorescence spectrometry. Coefficients of calibration dependences for intensity vs. element concentrations were calculated for Nd, Sr, and K by the least-squares technique. A linear approximation function was used in determining potassium and a parabolic approximation function was recommended in determining neodymium and strontium. The obtained dependences are characterized by low (<1%) relative approximation errors. In the analytical ranges (wt %) for K 0.863−8.892, Sr 8.41−38.03, and Nd 5.296−29.30, the standard deviations were 0.012−0.028, 0.008−0.098, and 0.05−0.27 respectively.</p>","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":1.0000,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Analytical Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1061934824700977","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The composition of solid solutions in the KNd(SO4)2·H2O–SrSO4·0.5H2O system, synthesized from aqueous solutions of KCl, NdCl3, SrCl2, and H2SO4, was studied by X-ray fluorescence spectrometry. Coefficients of calibration dependences for intensity vs. element concentrations were calculated for Nd, Sr, and K by the least-squares technique. A linear approximation function was used in determining potassium and a parabolic approximation function was recommended in determining neodymium and strontium. The obtained dependences are characterized by low (<1%) relative approximation errors. In the analytical ranges (wt %) for K 0.863−8.892, Sr 8.41−38.03, and Nd 5.296−29.30, the standard deviations were 0.012−0.028, 0.008−0.098, and 0.05−0.27 respectively.
期刊介绍:
The Journal of Analytical Chemistry is an international peer reviewed journal that covers theoretical and applied aspects of analytical chemistry; it informs the reader about new achievements in analytical methods, instruments and reagents. Ample space is devoted to problems arising in the analysis of vital media such as water and air. Consideration is given to the detection and determination of metal ions, anions, and various organic substances. The journal welcomes manuscripts from all countries in the English or Russian language.