Nanorod structure tuning and defect engineering of MoOx for high-performance SERS substrates†

Abstract

In recent years, surface-enhanced Raman scattering (SERS) based on metal oxide semiconductors has been an active area of research and development, attracting significant scientific interest. These SERS substrates are known as plasmon-free SERS substrates because they are not based on noble metal nanoparticles but mainly on the defects, structure, and surface morphology of semiconductors to enhance the Raman signal. In this study, we fabricated a SERS substrate based on molybdenum oxide, using reactive DC magnetron sputtering and then used different simple and effective strategies to enhance the Raman signal. The results show that nanorod structure, oxygen deficiency engineering, phase engineering, and optical properties can be easily controlled by varying sputtering time and annealing time of MoO_x SERS substrates. The analysis methods XRD, PL, and Raman show that with the optimal fabricated conditions. The presence of oxygen defects and a mixed MoO₃, Mo₉O₂₆ phase structure in as well as the nanorod structure of MoO_x SERS substrates could likely enhance Raman signals via a chemical mechanism (CM) and electromagnetic mechanism (EM). The MoO_x SERS substrates were also used to detect R6G at low concentrations, with an EF of 1.14 × 10⁶ (at 0.01 ppm), LOD of 0.01 ppm, and good temporal stability and reproducibility.