Enhanced mechanical and electrical properties of single-walled carbon nanotube fibers via electric field-assisted wet spinning

Abstract

Researchers have been working on creating fibers from single-walled carbon nanotubes (SWCNTs) that have optimal properties at the molecular level. However, the prepared SWCNT fibers have showed much lower properties than the ones predicted by theory because the interactions between SWCNTs and SWCNT bundles were not strong enough due to the poor alignment of SWCNTs in the fibers. In this study we improved the mechanical and electrical properties of the SWCNT fibers by using an electric field during the wet spinning process. The electric field, which was applied to the top of the syringe plunger and the tip of the spinneret, oriented the SWCNTs in the chlorosulfonic acid dope solution in a nozzle system, and made them more compact. The SWCNT fibers produced through our process exhibited a significant improvement in their properties. Specifically, we observed a 117.5 % increase in tensile strength and a 140.5 % increase in electrical conductivity. Importantly, these enhancements were achieved without the need for any additional post-treatments. This clearly demonstrates the effectiveness of our current wet spinning method.