Impact of biomass burning on air quality: A case study of the agricultural region in South Korea

Abstract

Various combustion processes occur concurrently during biomass burning events, emitting a complex mixture of particulate and gaseous pollutants into the atmosphere. These emissions undergo chemical transformations facilitated by factors such as solar radiation and cloud formation, thereby altering the composition of aerosols. Additionally, these pollutants can affect the region of origin and neighboring countries, presenting regional and global environmental challenges. Therefore, precise evaluation of the particulate and gaseous pollutants emitted during biomass burning is essential to formulate effective management strategies. This study aimed to assess the concentration and chemical characteristics of particulate matter emitted during biomass burning in South Korea. On June 7, 2021, a research flight was conducted utilizing a High Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) and a Single Particle Soot Photometer (SP2) for airborne measurements over South Korea inland areas. For data analysis based on administrative regions, the flight path was divided into four major areas (Areas A, B, C, and D). During the research flight, evidence of biomass burning events was observed primarily in Area C. A positive matrix factorization (PMF) analysis categorized the organic aerosols (OA) into five factors: biomass burning OA (BBOA), hydrocarbon-like OA (HOA1, HOA2), low-oxidized oxygenated OA (LO-OOA), and more-oxidized OOA (MO-OOA). Across all areas, MO-OOA accounted for the highest proportion of aerosols, whereas BBOA dominated in Area C at 23.8%, indicating the significant influence of biomass burning in this region. Instead of running a PMF analysis with all measurement data, a BBOA formula was derived from the previous study and this one. This allows us to estimate BBOA concentration without running PMF.