{"title":"Effect of a Zr source addition on the microstructure of Al-SiC composites elaborated by the Laser Powder Bed Fusion (L-PBF) process","authors":"Marie-Reine Manlay , Camille Flament , Stéphane Gossé , Mathieu Soulier , Jean-Paul Garandet","doi":"10.1016/j.matchar.2024.114472","DOIUrl":null,"url":null,"abstract":"<div><div>The present work focuses on the effect of the addition of a zirconium source on the microstructure of Al-SiC composites produced by Laser Powder Bed Fusion (L-PBF). More specifically, the aim is to address the issue of the SiC decomposition into the water-soluble aluminum carbide Al<sub>4</sub>C<sub>3</sub> in Al-SiC composites produced by L-PBF, with the objective of limiting its formation by adding another element to the system. To this end, AlSi<sub>7</sub>Mg<sub>0.6</sub>-SiC-ZrO<sub>2</sub> composite powders are successfully prepared and printed in a standard L-PBF equipment. The resulting parts are then thoroughly characterized, in order to understand the physico-chemical mechanisms involved during the L-PBF process. The results show a decrease in the Al<sub>4</sub>C<sub>3</sub> amount by ZrC formation. Another important result is that bulk composites exhibit a fully equiaxed microstructure attributed to the τ<sub>1</sub> (Al,Si)<sub>3</sub>Zr ternary phase, with all the characteristics of a good nucleating agent for aluminum phase. To support these microstructure experimental results, a first version of a quaternary Al-Zr-Si-C thermodynamic database was developed using the Calphad method. These calculations enable to establish a solidification path providing information on the phases that may form after heat treatment of L-PBF materials.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"218 ","pages":"Article 114472"},"PeriodicalIF":4.8000,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Characterization","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1044580324008532","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CHARACTERIZATION & TESTING","Score":null,"Total":0}
引用次数: 0
Abstract
The present work focuses on the effect of the addition of a zirconium source on the microstructure of Al-SiC composites produced by Laser Powder Bed Fusion (L-PBF). More specifically, the aim is to address the issue of the SiC decomposition into the water-soluble aluminum carbide Al4C3 in Al-SiC composites produced by L-PBF, with the objective of limiting its formation by adding another element to the system. To this end, AlSi7Mg0.6-SiC-ZrO2 composite powders are successfully prepared and printed in a standard L-PBF equipment. The resulting parts are then thoroughly characterized, in order to understand the physico-chemical mechanisms involved during the L-PBF process. The results show a decrease in the Al4C3 amount by ZrC formation. Another important result is that bulk composites exhibit a fully equiaxed microstructure attributed to the τ1 (Al,Si)3Zr ternary phase, with all the characteristics of a good nucleating agent for aluminum phase. To support these microstructure experimental results, a first version of a quaternary Al-Zr-Si-C thermodynamic database was developed using the Calphad method. These calculations enable to establish a solidification path providing information on the phases that may form after heat treatment of L-PBF materials.
期刊介绍:
Materials Characterization features original articles and state-of-the-art reviews on theoretical and practical aspects of the structure and behaviour of materials.
The Journal focuses on all characterization techniques, including all forms of microscopy (light, electron, acoustic, etc.,) and analysis (especially microanalysis and surface analytical techniques). Developments in both this wide range of techniques and their application to the quantification of the microstructure of materials are essential facets of the Journal.
The Journal provides the Materials Scientist/Engineer with up-to-date information on many types of materials with an underlying theme of explaining the behavior of materials using novel approaches. Materials covered by the journal include:
Metals & Alloys
Ceramics
Nanomaterials
Biomedical materials
Optical materials
Composites
Natural Materials.