{"title":"The enhancement detection method based on the Fabry–Pérot cavity using terahertz frequency-domain spectroscopy","authors":"Yubo Wu , Kanglong Chen , Ayesha Kosar Fahad , Haorang Wang , Xiaoping Zheng , Cunjun Ruan","doi":"10.1016/j.saa.2024.125293","DOIUrl":null,"url":null,"abstract":"<div><div>This article demonstrates a simple, efficient, and low-cost gas detection method for gases with absorption peaks in the terahertz range. A modes-adjustable Fabry–Pérot cavity is designed. By adjusting the length of the cavity, the center resonant frequency of the cavity can be coupled to the gas absorption peak. This kind of coupling can greatly enhance gas detection. To detect gas absorption peaks, we choose terahertz frequency domain spectroscopy (THz-FDS), whose frequency resolution can be up to the MHz level. Vapor is selected to verify the coupling phenomenon. The resonant frequency of the cavity is modified to couple to 0.56 THz, the absorption peak of vapor. Experiments are conducted at different humidity levels, the humidity is controlled by the supersaturated salt solution. Results indicate that at a humidity level of 15 %, the coupling effect can enhance the detectability of vapor by approximately 167 %, and this enhancement effect diminishes as humidity increases. We analyze the effect of different modes on the coupling and find that the high modes can make the coupling easier, but have little effect on the enhancement. Furthermore, the method is used to detect biomolecule-α-tyrosine to ensure it has wide applicability. This method can be used to detect substances with absorption peaks in the THz regime, especially for low-concentration gas.</div></div>","PeriodicalId":433,"journal":{"name":"Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy","volume":"327 ","pages":"Article 125293"},"PeriodicalIF":4.3000,"publicationDate":"2024-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1386142524014598","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"SPECTROSCOPY","Score":null,"Total":0}
引用次数: 0
Abstract
This article demonstrates a simple, efficient, and low-cost gas detection method for gases with absorption peaks in the terahertz range. A modes-adjustable Fabry–Pérot cavity is designed. By adjusting the length of the cavity, the center resonant frequency of the cavity can be coupled to the gas absorption peak. This kind of coupling can greatly enhance gas detection. To detect gas absorption peaks, we choose terahertz frequency domain spectroscopy (THz-FDS), whose frequency resolution can be up to the MHz level. Vapor is selected to verify the coupling phenomenon. The resonant frequency of the cavity is modified to couple to 0.56 THz, the absorption peak of vapor. Experiments are conducted at different humidity levels, the humidity is controlled by the supersaturated salt solution. Results indicate that at a humidity level of 15 %, the coupling effect can enhance the detectability of vapor by approximately 167 %, and this enhancement effect diminishes as humidity increases. We analyze the effect of different modes on the coupling and find that the high modes can make the coupling easier, but have little effect on the enhancement. Furthermore, the method is used to detect biomolecule-α-tyrosine to ensure it has wide applicability. This method can be used to detect substances with absorption peaks in the THz regime, especially for low-concentration gas.
期刊介绍:
Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy (SAA) is an interdisciplinary journal which spans from basic to applied aspects of optical spectroscopy in chemistry, medicine, biology, and materials science.
The journal publishes original scientific papers that feature high-quality spectroscopic data and analysis. From the broad range of optical spectroscopies, the emphasis is on electronic, vibrational or rotational spectra of molecules, rather than on spectroscopy based on magnetic moments.
Criteria for publication in SAA are novelty, uniqueness, and outstanding quality. Routine applications of spectroscopic techniques and computational methods are not appropriate.
Topics of particular interest of Spectrochimica Acta Part A include, but are not limited to:
Spectroscopy and dynamics of bioanalytical, biomedical, environmental, and atmospheric sciences,
Novel experimental techniques or instrumentation for molecular spectroscopy,
Novel theoretical and computational methods,
Novel applications in photochemistry and photobiology,
Novel interpretational approaches as well as advances in data analysis based on electronic or vibrational spectroscopy.