Pooja Dhiman, Jayati Sharma, Mohammad Rafe Hatshan, Ayman A. Ghfar, Amit Kumar, Gaurav Sharma
{"title":"Rare Earth Ions Doping Enhanced Photocatalytic Activity of Bi5O7I for Superior Visible Light Driven Degradation of Ciprofloxacin","authors":"Pooja Dhiman, Jayati Sharma, Mohammad Rafe Hatshan, Ayman A. Ghfar, Amit Kumar, Gaurav Sharma","doi":"10.1007/s11270-024-07570-y","DOIUrl":null,"url":null,"abstract":"<div><p>Enhancing the efficacy of semiconductor photocatalysts through the doping of rare-earth ions is a viable approach for regulating their behaviour. The current study employs a solvothermal method followed by calcination to produce Bi<sub>5</sub>O<sub>7</sub>I photocatalysts doped with rare earth elements (Sm, Nd, and Dy). Ciprofloxacin was used as the target pollutant for all produced catalysts. Among all, Sm-doped Bi<sub>5</sub>O<sub>7</sub>I exhibited optimal degradation efficiency against ciprofloxacin. Sm doping was identified to be responsible for increased visible light absorption and enhanced separation of light-induced carriers, leading to increased performance in photocatalysis. The Sm doped Bi<sub>5</sub>O<sub>7</sub>I also showed good adaptation to higher initial ciprofloxacin concentrations and the requisite photodegradation stability after four cycles. Furthermore, the up-conversion luminescence feature of Sm increased the catalyst's visible light usage range. The scavenging experiment identified ·O<sub>2</sub><sup>−</sup>, h<sup>+</sup>, and <sup>1</sup>O<sub>2</sub> as active chemicals in the photocatalytic degradation of ciprofloxacin. Based on this fact, a possible degradation mechanism was postulated. This work may serve as a guide for creating doped bismuth-rich halides for waste water remediation.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 12","pages":""},"PeriodicalIF":3.8000,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Water, Air, & Soil Pollution","FirstCategoryId":"6","ListUrlMain":"https://link.springer.com/article/10.1007/s11270-024-07570-y","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 0
Abstract
Enhancing the efficacy of semiconductor photocatalysts through the doping of rare-earth ions is a viable approach for regulating their behaviour. The current study employs a solvothermal method followed by calcination to produce Bi5O7I photocatalysts doped with rare earth elements (Sm, Nd, and Dy). Ciprofloxacin was used as the target pollutant for all produced catalysts. Among all, Sm-doped Bi5O7I exhibited optimal degradation efficiency against ciprofloxacin. Sm doping was identified to be responsible for increased visible light absorption and enhanced separation of light-induced carriers, leading to increased performance in photocatalysis. The Sm doped Bi5O7I also showed good adaptation to higher initial ciprofloxacin concentrations and the requisite photodegradation stability after four cycles. Furthermore, the up-conversion luminescence feature of Sm increased the catalyst's visible light usage range. The scavenging experiment identified ·O2−, h+, and 1O2 as active chemicals in the photocatalytic degradation of ciprofloxacin. Based on this fact, a possible degradation mechanism was postulated. This work may serve as a guide for creating doped bismuth-rich halides for waste water remediation.
期刊介绍:
Water, Air, & Soil Pollution is an international, interdisciplinary journal on all aspects of pollution and solutions to pollution in the biosphere. This includes chemical, physical and biological processes affecting flora, fauna, water, air and soil in relation to environmental pollution. Because of its scope, the subject areas are diverse and include all aspects of pollution sources, transport, deposition, accumulation, acid precipitation, atmospheric pollution, metals, aquatic pollution including marine pollution and ground water, waste water, pesticides, soil pollution, sewage, sediment pollution, forestry pollution, effects of pollutants on humans, vegetation, fish, aquatic species, micro-organisms, and animals, environmental and molecular toxicology applied to pollution research, biosensors, global and climate change, ecological implications of pollution and pollution models. Water, Air, & Soil Pollution also publishes manuscripts on novel methods used in the study of environmental pollutants, environmental toxicology, environmental biology, novel environmental engineering related to pollution, biodiversity as influenced by pollution, novel environmental biotechnology as applied to pollution (e.g. bioremediation), environmental modelling and biorestoration of polluted environments.
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Water, Air, & Soil Pollution publishes research papers; review articles; mini-reviews; and book reviews.