Hofmeister effect induced water activation of hydrogel and its applications for the accelerated solar evaporation in brine

Abstract

Solar-driven desalination has emerged as a promising approach to address water scarcity caused by the decreasing supply of freshwater. Reducing the enthalpy of water vaporization is crucial for enhancing the efficiency of solar-powered desalination. In this study, inspired by the Hofmeister effect, we developed a highly hydratable network hydrogel evaporator to achieve a superior evaporation rate in brine compared with pure water. The evaporator comprised a carbonized layer as the photothermal layer and a chitosan aerogel hydrogel as the hydratable matrix. The hydrogel exhibited a dramatically reduced vaporization enthalpy of 1397 J/g and a significant evaporation rate of 2.38 kg m⁻² h⁻¹ when exposed to seawater. These results demonstrated the superior performance of hydrogel compared with pure water (1.91 kg m⁻² h⁻¹). Excellent evaporation rates and outstanding salt resistance ensured efficient coordination for practical long-term desalination applications. Further investigations revealed that the remarkable evaporation performance of the carbonized chitosan (CCS) hydrogel in brine environments was attributed to its hydrability, which was regulated by Cl⁻. According to the Hofmeister effect, Cl⁻ accelerated the hydration chemistry in CCS and suppressed the associated crystallinity, which resulted in a lower enthalpy of vaporisation owing to a higher amount of intermediate water. With its superior evaporation performance in brine and comprehensive theoretical simulation analysis, this study presents an achievable and economical strategy for simultaneously addressing the water and energy crises.