Seed-Assisted Hydrothermal Synthesis of Monodispersed Au@C Core–Shell Nanostructures for Enhancing Thermal Diffusivity of Water-Based Nanofluids

Abstract

Au@C core–shell nanostructures (Au@C-NS) were synthesized through a low-temperature seed-assisted hydrothermal approach using glucose as carbon source. The material characterization and chemical analysis confirm that the synthesis method allows to obtain uniform core–shell nanostructures constituted by a crystalline metal core and an amorphous carbon shell. Depending on the synthesis conditions, their average size ranges from 146 nm to 342 nm with relative standard deviation as low as 7 %. It is proposed that the characteristic monodispersity results due to a high nucleation rate of the carbon phase at the liquid–solid interface. The obtained monodisperse Au@C-NS were used to prepare water-based nanofluids with superior heat transport properties. The thermal lens analysis shows that the thermal diffusivity of Au@C nanofluids is 9.5 % and 31.3 % higher than their Au nanofluids counterparts and pure water, respectively, at particle concentration of 285 × 10¹¹ ml⁻¹. Phonon-related interactions at the metal cores and carbon shells interfaces are proposed as the heat transport mechanism behind the thermal diffusivity enhancement of the Au@C water-based nanofluids.