The Influence of Particle Size and Calcium Content on Performance Characteristics of Metakaolin- and Fly-Ash-Based Geopolymer Gels.

Abstract

This research systematically investigates the influence of raw material particle size and calcium content on the geopolymerization process to gain insight into the physical and mechanical properties of geopolymer gels, including setting time, fluidity, pore structure, compressive strength, and leaching characteristics of encapsulated Cr³⁺ heavy metal ions. Utilizing a diverse range of particle sizes of metakaolin (MK; 3.75, 7.5, and 12 µm) and fly ash (FA; 18, 45, and 75 µm), along with varied calcium levels, this study assesses the dual impact of these factors on the final properties of both metakaolin- and fly-ash-based geopolymers. Employing sophisticated analytical techniques such as Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), and Nuclear Magnetic Resonance (NMR), the research meticulously documents alterations in chemical bonding, micro-morphology, and pore structures. Key findings reveal that reducing the size of MK and FA particles to 3.75 and 18 µm, respectively, enhances the compressive strength of their matrices by 128.37 and 297.58%, respectively, compared to their original values (63.59 and 33.87 MPa, respectively) at larger particle sizes. While smaller particle sizes significantly bolster compressive strength, they adversely affect slurry flow and reduce the leaching rates of Cr³⁺ from MK- and FA-based matrices, reaching 0.42 and 0.75 mg/L at 3.75 and 18 µm, respectively. Conversely, increased calcium content markedly enhances setting times and contributes to the formation of dense microstructures through the production of calcium aluminate silicate hydrate (C-A-S-H) gels, thus improving the overall curing performance and durability of the materials. These insights underline the importance of fine-tuning particle size and calcium content to optimize geopolymer formulations, offering substantial benefits for varied engineering applications and promoting more sustainable construction practices.