Junsheng Hou, Bingxin You, Ruiqi Lv, Xinxin Zhang, Jinyang Shen, Jiaojiao Li, Xi Zuo, Qiang Liu
{"title":"Synthesis of 1,4-benzodioxepines <i>via</i> electrochemical oxyselenenylation of 2-<i>O</i>-tethered alkenyl phenylmethanol and diselenides.","authors":"Junsheng Hou, Bingxin You, Ruiqi Lv, Xinxin Zhang, Jinyang Shen, Jiaojiao Li, Xi Zuo, Qiang Liu","doi":"10.1039/d4ob01483a","DOIUrl":null,"url":null,"abstract":"<p><p>A highly efficient methodology has been developed for the synthesis of 1,4-benzodioxepines through electrochemical oxyselenenylation of 2-<i>O</i>-tethered alkenyl phenylmethanol and diselenides under external oxidant-free conditions at room temperature. Experimental evidence supports this transformation to occur <i>via</i> a radical mechanism.</p>","PeriodicalId":2,"journal":{"name":"ACS Applied Bio Materials","volume":null,"pages":null},"PeriodicalIF":4.6000,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Bio Materials","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4ob01483a","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, BIOMATERIALS","Score":null,"Total":0}
引用次数: 0
Abstract
A highly efficient methodology has been developed for the synthesis of 1,4-benzodioxepines through electrochemical oxyselenenylation of 2-O-tethered alkenyl phenylmethanol and diselenides under external oxidant-free conditions at room temperature. Experimental evidence supports this transformation to occur via a radical mechanism.
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