Synthesis of 1,4-benzodioxepines via electrochemical oxyselenenylation of 2-O-tethered alkenyl phenylmethanol and diselenides†

IF 2.7 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2024-08-30 DOI:10.1039/d4ob01483a

Junsheng Hou , Bingxin You , Ruiqi Lv , Xinxin Zhang , Jinyang Shen , Jiaojiao Li , Xi Zuo , Qiang Liu

引用次数: 0

Abstract

A highly efficient methodology has been developed for the synthesis of 1,4-benzodioxepines through electrochemical oxyselenenylation of 2-O-tethered alkenyl phenylmethanol and diselenides under external oxidant-free conditions at room temperature. Experimental evidence supports this transformation to occur via a radical mechanism.

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通过电化学氧化 2-O 系烯基苯基甲醇和二硒化物合成 1,4-苯并二氧杂环庚烷。

在室温无氧化剂的外部条件下，通过对 2-O 系烯基苯基甲醇和二硒化物进行电化学氧化硒化反应，开发出了一种高效合成 1,4-苯并二氧杂环庚烷的方法。实验证明这种转化是通过自由基机制发生的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.