A portable fluorescence sensing system for timely onsite perfluorooctane sulfonate detection based on an aggregate induced emission fluorescence sensor.

Abstract

Perfluorooctane sulfonate (PFOS), a ubiquitous persistent organic pollutant, has aroused growing concern due to its adverse effects on human health. Timely onsite monitoring of PFOS in heavily contaminated areas is crucial for effective pollution management and prevention of its spread. However, relevant PFOS detection methods have rarely been reported. Herein, we developed a fluorescence sensing system capable of achieving timely onsite detection of PFOS under outdoor conditions. First, aggregate induced emission (AIE) fluorescence sensors, TPE-PAs, were synthesized. The optimized sensor could selectively interact with PFOS through electrostatic attraction and hydrogen bonding and exhibited prominent fluorescence enhancement after treating with PFOS. There was a good linear relationship between the fluorescence enhancement and PFOS concentration in the range of 0.05-30 ppm, and the limit of detection was measured to be 0.047 ppm. In addition, owing to the AIE fluorescence mechanism and high concentration of TPE-PAs in the sensing medium, the sensor demonstrated excellent anti-interference performance. Second, we developed a portable fluorometer, by modifying the power supply and sample cell of a tiny fluorometer, and further integrated this modified fluorometer, the prepared fluorescence sensor, standard PFOS solutions and other consumables into a portable test system. This test system showed good detection accuracy and reliability and successfully achieved timely onsite PFOS detection in real water samples.