Layer-by-layer assembled nanowire networks enable graph-theoretical design of multifunctional coatings

IF 17.3 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
Matter Pub Date : 2024-10-25 DOI:10.1016/j.matt.2024.09.014
Wenbing Wu, Alain Kadar, Sang Hyun Lee, Hong Ju Jung, Bum Chul Park, Jeffery E. Raymond, Thomas K. Tsotsis, Carlos E.S. Cesnik, Sharon C. Glotzer, Valerie Goss, Nicholas A. Kotov
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引用次数: 0

Abstract

Complex multifunctional coatings combining order and disorder are central for information, biomedical, transportation, and energy technologies. Their scalable fabrication is possible using nanostructured composites made by layer-by-layer assembly (LBL). Here, we show that structural descriptions encompassing their nonrandom disorder and related property-focused design are possible using graph theory (GT). Two-dimensional images of LBL films of silver and gold nanowires (NWs) were used to calculate GT representations. We found that random stick computational models often used to describe NW, nanofiber, and nanotube materials give inaccurate predictions of their structure. Concurrently, image-informed GT models accurately predict the structure and properties of the LBL films, including the unexpected nonlinearity of charge transport vs. LBL cycles. The conductivity anisotropy in LBL composites, not readily detectable with microscopy, was accurately predicted using GT models. Spray-assisted LBL offers the direct translation of GT predictions to additive, scalable coatings for drones and potentially other technologies.

Abstract Image

逐层组装的纳米线网络实现了多功能涂层的图论设计
有序与无序相结合的复杂多功能涂层是信息、生物医学、交通和能源技术的核心。利用逐层组装(LBL)技术制造的纳米结构复合材料可以实现这些涂层的规模化制造。在这里,我们展示了利用图论(GT)可以实现包含非随机无序和相关特性设计的结构描述。银纳米线和金纳米线 (NW) LBL 薄膜的二维图像被用来计算 GT 表示。我们发现,通常用于描述纳米线、纳米纤维和纳米管材料的随机棒计算模型对其结构的预测并不准确。同时,图像信息 GT 模型能准确预测 LBL 薄膜的结构和特性,包括电荷传输与 LBL 周期之间意想不到的非线性关系。LBL 复合材料中的电导率各向异性在显微镜下不易察觉,但通过 GT 模型却能准确预测。喷涂辅助 LBL 可将 GT 预测直接转化为用于无人机和其他潜在技术的可扩展添加涂层。
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来源期刊
Matter
Matter MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
26.30
自引率
2.60%
发文量
367
期刊介绍: Matter, a monthly journal affiliated with Cell, spans the broad field of materials science from nano to macro levels,covering fundamentals to applications. Embracing groundbreaking technologies,it includes full-length research articles,reviews, perspectives,previews, opinions, personnel stories, and general editorial content. Matter aims to be the primary resource for researchers in academia and industry, inspiring the next generation of materials scientists.
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