Gold nanoparticle-decorated amorphous carbon for oxidative cyclization of anthranilamide and aryl alcohols†

IF 3.5 3区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR
The Thai Nguyen, Huyen-Tran Thi Nguyen, Thu Anh Nguyen, Khuong Quoc Vo and Phuong Hoang Tran
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引用次数: 0

Abstract

Herein, gold nanoparticle-decorated amorphous carbon (Au/AC) was prepared by reducing chloroauric acid and layering it on amorphous carbon. The characteristics of Au/AC were examined using FT-IR, XRD, TGA, SEM, EDS, and XPS. To assess its catalytic activity, Au/AC was tested in a reaction involving anthranilamide and benzyl alcohol at 110 °C for 24 hours. This reaction yielded various 2-phenylquinazolin-4(3H)-one derivatives in moderate to good yields (44–80%). Furthermore, control experiments were conducted to demonstrate the oxidation and cyclization functions of Au/AC. Noteworthy aspects of this approach included the ease of isolating Au/AC (via recrystallization) and the ability to recycle it.

Abstract Image

Abstract Image

金纳米粒子装饰的无定形碳用于蒽胺和芳基醇的氧化环化。
本文通过还原氯金酸并在无定形碳上分层,制备了金纳米粒子装饰无定形碳(Au/AC)。利用傅立叶变换红外光谱、X射线衍射、热重分析、扫描电镜、电致发光和 XPS 对 Au/AC 的特性进行了研究。为了评估 Au/AC 的催化活性,在涉及蒽酰胺和苯甲醇的反应中对 Au/AC 进行了测试,反应温度为 110 °C,时间为 24 小时。该反应生成了各种 2-苯基喹唑啉-4(3H)-酮衍生物,收率从中等到良好(44-80%)不等。此外,还进行了对照实验,以证明 Au/AC 的氧化和环化功能。该方法值得注意的方面包括:Au/AC 易于分离(通过重结晶),并且能够循环利用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Dalton Transactions
Dalton Transactions 化学-无机化学与核化学
CiteScore
6.60
自引率
7.50%
发文量
1832
审稿时长
1.5 months
期刊介绍: Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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