{"title":"Fluorescent Tetraphenylethylene-Based Cerium Metal–Organic Frameworks for White-Light-Emitting Diodes","authors":"Si-Si Zhao, Si-Hui Wang, Qi Sun, Hang Zhang, Jing-Wei Zhao, Xin-Yu Wang, Zhen Zhao","doi":"10.1021/acsami.4c14046","DOIUrl":null,"url":null,"abstract":"Discovery of highly efficient and thermal stable phosphors is the focus of the studies in phosphor-converted white light-emitting diodes (LEDs). Herein, a tetraphenylethylene-based cerium metal–organic framework (<b>SYNU-2</b>) was synthesized and characterized. The intricate architecture of <b>SYNU-2</b> shows an overall 3D → 3D 2-fold interpenetration framework. <b>SYNU-2</b> exhibited good luminescence properties, and its latent fingerprint developer was prepared, which showed good fluorescence and stability under ultraviolet (UV) radiation. It is worth noting that a prototype WLED device can be designed using <b>SYNU-2</b> and red phosphors (Ca,Sr)AlSiN<sub>3</sub>:Eu<sup>2+</sup> with CIE coordinates of (0.33, 0.33) at an applied 3 V bias.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":null,"pages":null},"PeriodicalIF":8.3000,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Materials & Interfaces","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1021/acsami.4c14046","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Discovery of highly efficient and thermal stable phosphors is the focus of the studies in phosphor-converted white light-emitting diodes (LEDs). Herein, a tetraphenylethylene-based cerium metal–organic framework (SYNU-2) was synthesized and characterized. The intricate architecture of SYNU-2 shows an overall 3D → 3D 2-fold interpenetration framework. SYNU-2 exhibited good luminescence properties, and its latent fingerprint developer was prepared, which showed good fluorescence and stability under ultraviolet (UV) radiation. It is worth noting that a prototype WLED device can be designed using SYNU-2 and red phosphors (Ca,Sr)AlSiN3:Eu2+ with CIE coordinates of (0.33, 0.33) at an applied 3 V bias.
期刊介绍:
ACS Applied Materials & Interfaces is a leading interdisciplinary journal that brings together chemists, engineers, physicists, and biologists to explore the development and utilization of newly-discovered materials and interfacial processes for specific applications. Our journal has experienced remarkable growth since its establishment in 2009, both in terms of the number of articles published and the impact of the research showcased. We are proud to foster a truly global community, with the majority of published articles originating from outside the United States, reflecting the rapid growth of applied research worldwide.