Failure analysis of ternary lithium-ion batteries throughout the entire life cycling at high temperature

Abstract

The operation life is a key factor affecting the cost and application of lithium-ion batteries. This article investigates the changes in discharge capacity, median voltage, and full charge DC internal resistance of the 25Ah ternary (LiNi_0.5Mn_0.3Co_0.2O₂/graphite) lithium-ion battery during full life cycles at 45 °C and 2000 cycles at 25 °C for comparison. The batteries before and after cycling were disassembled, and the structure, morphology, interface characteristics, element content of the cathode and anode plates of the battery were characterized. By analyzing the failure factors of the performance of the ternary batteries during the 45 °C cycling, a reaction mechanism for the rapid decline of high-temperature cycling performance of ternary batteries has been proposed. The results show that the performance degradation of the ternary lithium-ion batteries in the whole life operated at high temperature is characterized by slow decline in the initial stage and rapid drop in the latter stage. Further analysis of physical and chemical performance revealed irreversible damage to both the cathode and anode. The dissolution of transition metal ions from the cathode and their deposition on the anode surface catalyze the decomposition of electrolyte solvents to produce a large amount of gas. Gassing, accompanied by the deposition of Li₂CO₃ and the thickening of SEI, leads to an increase in the internal resistance of the battery. The coupling between gassing and increased internal resistance is responsible for the rapid drop in the performance of the ternary batteries during high-temperature cycling.