Mohammed Mamor , Marie Pierre Chauvat , Pierre Ruterana
{"title":"Electrical and structural investigation of Pt/n-type GaN Schottky contacts: The possible origin of inhomogeneous barrier","authors":"Mohammed Mamor , Marie Pierre Chauvat , Pierre Ruterana","doi":"10.1016/j.mseb.2024.117756","DOIUrl":null,"url":null,"abstract":"<div><div>An ideal metal/GaN interface is not usually possible and the surface states are often present at such interface and therefore affect the Schottky barrier diode (SBD) performance. In this work the interface states in Pt/n-type GaN SBD were extracted using temperature dependent forward current–voltage (<em>I</em>-<em>V</em>-<em>T</em>) characteristics over a large temperature range (80–400 K). The energy profile distribution of the density of interface states <em>N</em><sub>SS</sub> (<em>E</em>) and its dependence on the temperature were determined from the bias and temperature dependence of the measured effective barrier height <span><math><mrow><msub><mrow><mi>Ф</mi></mrow><mrow><mn>0</mn><mi>b</mi><mi>n</mi></mrow></msub><mo>(</mo><mi>V</mi><mo>,</mo><mi>T</mi><mo>)</mo></mrow></math></span> and ideality factor <em>n</em> (<em>V</em>, <em>T</em>). It is shown that the interface states density at room temperature decreases with increasing energy with respect to the conduction band. It is shown that the effective Schottky barrier height (SBH) and ideality factor are correlated to the density of interface states. This result suggests that interface states density contributes to barrier inhomogeneities in Pt/n-type GaN SBD. Fourier transform deep level transient spectroscopy (FT-DLTS) has been employed to extract qualitative information about the native defects present in as-grown n-type GaN. From FT-DLTS, two prominent native defects D<sub>2</sub> and D<sub>3</sub> were observed in GaN. The defect D<sub>2</sub> located at <em>E</em><sub>C</sub>- 0.56 eV could be associated with impurity at Ga site. The defect D<sub>3</sub> located at <em>E</em><sub>C</sub>- 0.26 eV has been assigned to nitrogen-related energy level. These native defects are interpreted as responsible of the existence of interface states and then to the barrier inhomogeneities at Pt/n-type GaN contacts. Furthermore, other possible origins of the interface states at Pt/n-type GaN interface are discussed in terms of the threading dislocations inside the GaN templates that reach the surface and other possible irregularities at this interface.</div></div>","PeriodicalId":18233,"journal":{"name":"Materials Science and Engineering B-advanced Functional Solid-state Materials","volume":"310 ","pages":"Article 117756"},"PeriodicalIF":3.9000,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Science and Engineering B-advanced Functional Solid-state Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0921510724005853","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
An ideal metal/GaN interface is not usually possible and the surface states are often present at such interface and therefore affect the Schottky barrier diode (SBD) performance. In this work the interface states in Pt/n-type GaN SBD were extracted using temperature dependent forward current–voltage (I-V-T) characteristics over a large temperature range (80–400 K). The energy profile distribution of the density of interface states NSS (E) and its dependence on the temperature were determined from the bias and temperature dependence of the measured effective barrier height and ideality factor n (V, T). It is shown that the interface states density at room temperature decreases with increasing energy with respect to the conduction band. It is shown that the effective Schottky barrier height (SBH) and ideality factor are correlated to the density of interface states. This result suggests that interface states density contributes to barrier inhomogeneities in Pt/n-type GaN SBD. Fourier transform deep level transient spectroscopy (FT-DLTS) has been employed to extract qualitative information about the native defects present in as-grown n-type GaN. From FT-DLTS, two prominent native defects D2 and D3 were observed in GaN. The defect D2 located at EC- 0.56 eV could be associated with impurity at Ga site. The defect D3 located at EC- 0.26 eV has been assigned to nitrogen-related energy level. These native defects are interpreted as responsible of the existence of interface states and then to the barrier inhomogeneities at Pt/n-type GaN contacts. Furthermore, other possible origins of the interface states at Pt/n-type GaN interface are discussed in terms of the threading dislocations inside the GaN templates that reach the surface and other possible irregularities at this interface.
期刊介绍:
The journal provides an international medium for the publication of theoretical and experimental studies and reviews related to the electronic, electrochemical, ionic, magnetic, optical, and biosensing properties of solid state materials in bulk, thin film and particulate forms. Papers dealing with synthesis, processing, characterization, structure, physical properties and computational aspects of nano-crystalline, crystalline, amorphous and glassy forms of ceramics, semiconductors, layered insertion compounds, low-dimensional compounds and systems, fast-ion conductors, polymers and dielectrics are viewed as suitable for publication. Articles focused on nano-structured aspects of these advanced solid-state materials will also be considered suitable.