Luminescent o-carboranyl-containing molecules: A promising platform for stimuli-responsive smart materials

IF 4.1 3区工程技术 Q2 CHEMISTRY, APPLIED

Dyes and Pigments Pub Date : 2024-10-11 DOI:10.1016/j.dyepig.2024.112484

引用次数: 0

Abstract

o-Carborane, spherical-shaped 12-vertex boron cluster molecule bearing two adjacent carbons, plays an increasingly important role in multifunctional optoelectronic materials due to its appealing luminescent properties. The sterically and conjugately special natures enable the building block of o-carborane display unique emissive features of aggregation-induced emission (AIE), multi- and excimer-emission. Molecules with these features are highly sensitive to subtle environmental factors and broadly applicable in smart and sensory materials. In this paper, holistic and in-depth perspectives on those phenomenon features, the underlying mechanistic analyses, as well as associated applications are addressed on recently developed o-carboranyl molecules, aiming to bridge the phenomenon-mechanism-application gap and offering an up-to-date progress report.

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含邻硼烷基的发光分子：刺激响应型智能材料的前景广阔的平台

邻碳硼烷（o-Carborane）是一种球形的 12 刃硼簇分子，含有两个相邻的碳，因其诱人的发光特性，在多功能光电材料中发挥着越来越重要的作用。立体和共轭的特殊性质使得邻碳硼烷结构单元具有聚集诱导发射（AIE）、多发射和准分子发射等独特的发光特性。具有这些特征的分子对微妙的环境因素高度敏感，可广泛应用于智能和传感材料。本文从整体和深入的角度探讨了这些现象特征、基本机理分析以及最新开发的邻硼酰分子的相关应用，旨在弥合现象-机理-应用之间的差距，并提供一份最新进展报告。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Dyes and Pigments 工程技术-材料科学：纺织

CiteScore

8.20

自引率

13.30%

发文量

933

审稿时长

33 days

期刊介绍： Dyes and Pigments covers the scientific and technical aspects of the chemistry and physics of dyes, pigments and their intermediates. Emphasis is placed on the properties of the colouring matters themselves rather than on their applications or the system in which they may be applied. Thus the journal accepts research and review papers on the synthesis of dyes, pigments and intermediates, their physical or chemical properties, e.g. spectroscopic, surface, solution or solid state characteristics, the physical aspects of their preparation, e.g. precipitation, nucleation and growth, crystal formation, liquid crystalline characteristics, their photochemical, ecological or biological properties and the relationship between colour and chemical constitution. However, papers are considered which deal with the more fundamental aspects of colourant application and of the interactions of colourants with substrates or media. The journal will interest a wide variety of workers in a range of disciplines whose work involves dyes, pigments and their intermediates, and provides a platform for investigators with common interests but diverse fields of activity such as cosmetics, reprographics, dye and pigment synthesis, medical research, polymers, etc.