{"title":"Mutually Activated 2D Ti0.87O2/MXene Monolayers Through Electronic Compensation Effect as Highly Efficient Cathode Catalysts of Li–O2 Batteries","authors":"Dongmei Zhang, Guoliang Zhang, Runbo Liu, Ruonan Yang, Xia Li, Xiuqi Zhang, Han Yu, Pengxiang Zhang, Bao-Wen Li, Hua Hou, Zhanhu Guo, Feng Dang","doi":"10.1002/adfm.202414679","DOIUrl":null,"url":null,"abstract":"2D materials exhibit remarkable electrochemical performance as the cathode catalyst in lithium–oxygen batteries (LOBs). Their catalytic capability mainly derives from their 2D surface with tunable surface chemistry and unique electronic states. Herein, Ti<sub>0.87</sub>O<sub>2</sub> and Ti<sub>3</sub>C<sub>2</sub> MXene monolayers are applied to construct a face/face 2D heterostructure to enhance the catalytic performance in LOBs. It is demonstrated that electronic compensation from the O-terminated MXene to Ti<sub>0.87</sub>O<sub>2</sub> side is achieved through the built-in electric field and the overlap of Ti 3<i>d</i> and O 2<i>p</i> orbitals between Ti<sub>0.87</sub>O<sub>2</sub> and MXene units. As a result, the ORR/OER catalytic activity is improved in Ti<sub>0.87</sub>O<sub>2</sub>/MXene heterojunction due to the modulated <i>p</i>-band center that optimizes the <i>s–p</i> coupling with the key intermediate LiO<sub>2</sub>. The Ti<sub>0.87</sub>O<sub>2</sub>/MXene cathode presents a structural stability and long-term cycling life of 425 cycles (2534 h) at 200 mA g<sup>−1</sup> and 407 cycles at 1000 mA g<sup>−1</sup> with a fixed capacity of 600 mAh g<sup>−1</sup>, being nearly five and three times higher than that of pure Ti<sub>0.87</sub>O<sub>2</sub> and MXene cathodes, respectively.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":null,"pages":null},"PeriodicalIF":18.5000,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Functional Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/adfm.202414679","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
2D materials exhibit remarkable electrochemical performance as the cathode catalyst in lithium–oxygen batteries (LOBs). Their catalytic capability mainly derives from their 2D surface with tunable surface chemistry and unique electronic states. Herein, Ti0.87O2 and Ti3C2 MXene monolayers are applied to construct a face/face 2D heterostructure to enhance the catalytic performance in LOBs. It is demonstrated that electronic compensation from the O-terminated MXene to Ti0.87O2 side is achieved through the built-in electric field and the overlap of Ti 3d and O 2p orbitals between Ti0.87O2 and MXene units. As a result, the ORR/OER catalytic activity is improved in Ti0.87O2/MXene heterojunction due to the modulated p-band center that optimizes the s–p coupling with the key intermediate LiO2. The Ti0.87O2/MXene cathode presents a structural stability and long-term cycling life of 425 cycles (2534 h) at 200 mA g−1 and 407 cycles at 1000 mA g−1 with a fixed capacity of 600 mAh g−1, being nearly five and three times higher than that of pure Ti0.87O2 and MXene cathodes, respectively.
期刊介绍:
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