Reductive quenching of photosensitizer [Ru(bpy)3]2+ reveals the inhomogeneous distribution of sites in PAN polymer nanofibers for light-driven redox catalysis†
Svea M. Stepping, Nikita Vashistha, Sana Ullah, Poting Liu, Montaha Anjass and Benjamin Dietzek-Ivanšić
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引用次数: 0
Abstract
Integration of molecular photocatalysts into redox-inert polymers constitutes a path towards photocatalytically active, lightweight materials. In particular, electrospun polymer fibers hold potential due to their favorable surface-to-volume ratio and their straightforward fabrication. This study focuses on the polyacrylonitrile (PAN) fibers, into which the prototype photosensitizer (PS) ruthenium tris(bipyridine) [Ru(bpy)3]2+, has been embedded by electrospinning. Studying the interaction between the optically excited [Ru(bpy)3]2+ with a non-redox inert solvent within the nanofibers, we resolve a distribution of microenvironments, which differ by the extent to which the photosensitizer is exposed to the solvent. This results in a non-exponential decay of the complex's emission and pronounced differences in the transient absorption signals.
期刊介绍:
An international, peer-reviewed journal covering all of the chemical sciences, including multidisciplinary and emerging areas. RSC Advances is a gold open access journal allowing researchers free access to research articles, and offering an affordable open access publishing option for authors around the world.