{"title":"Sensor properties for Fe3+ and synthesis of new a bis –(3-(benzhydryloxy) propanoate) phthalocyaninato silicon (IV)","authors":"Derya Güngördü Solğun, Mehmet Salih Ağırtaş","doi":"10.1016/j.synthmet.2024.117760","DOIUrl":null,"url":null,"abstract":"<div><div>In this study, 3-(benzhydryloxy) propanoic acid (<strong>2</strong>) and bis –(3-(benzhydryloxy) propanoate) phthalocyaninato silicon (IV) (<strong>3</strong>) compounds were synthesized. Their compound structures were characterized with the help of IR, UV–visible, mass and <sup>1</sup>H NMR spectroscopy. Aggregation and solubility of the compounds were tested. Finally, the metal sensor property of the axial phthalocyanine compound was investigated against Cu<sup>2+</sup>, Fe<sup>3+</sup>, Mg<sup>2+</sup>, Mn<sup>2+</sup>, Na<sup>+</sup>, Zn<sup>2+</sup>, Ag<sup>+</sup>, Ba<sup>2+</sup>, Cd<sup>2+</sup> ions. It was determined that the compound was selectively sensitive to Fe<sup>3+</sup>. The optical detection of Fe<sup>3+</sup> ions in the presence of Cu<sup>2+</sup>, Fe<sup>3+</sup>, Mg<sup>2+</sup>, Mn<sup>2+</sup>, Na<sup>+</sup>, Zn<sup>2+</sup>, Ag<sup>+</sup>, Ba<sup>2+</sup>, Cd<sup>2+</sup> ions shows that this material can be used for easy and practical analysis.</div></div>","PeriodicalId":22245,"journal":{"name":"Synthetic Metals","volume":"309 ","pages":"Article 117760"},"PeriodicalIF":4.0000,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthetic Metals","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0379677924002224","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
In this study, 3-(benzhydryloxy) propanoic acid (2) and bis –(3-(benzhydryloxy) propanoate) phthalocyaninato silicon (IV) (3) compounds were synthesized. Their compound structures were characterized with the help of IR, UV–visible, mass and 1H NMR spectroscopy. Aggregation and solubility of the compounds were tested. Finally, the metal sensor property of the axial phthalocyanine compound was investigated against Cu2+, Fe3+, Mg2+, Mn2+, Na+, Zn2+, Ag+, Ba2+, Cd2+ ions. It was determined that the compound was selectively sensitive to Fe3+. The optical detection of Fe3+ ions in the presence of Cu2+, Fe3+, Mg2+, Mn2+, Na+, Zn2+, Ag+, Ba2+, Cd2+ ions shows that this material can be used for easy and practical analysis.
期刊介绍:
This journal is an international medium for the rapid publication of original research papers, short communications and subject reviews dealing with research on and applications of electronic polymers and electronic molecular materials including novel carbon architectures. These functional materials have the properties of metals, semiconductors or magnets and are distinguishable from elemental and alloy/binary metals, semiconductors and magnets.