{"title":"Acyl thiourea derivatives: Versatile tools for chemosensing and heavy metal remediation","authors":"Ozge Selcuk , Nangyallai Azizi , Mohammad Tahir Aminzai , Zeynel Seferoglu , Mauricio Federico Erben , Yahya Nural","doi":"10.1016/j.jece.2024.114279","DOIUrl":null,"url":null,"abstract":"<div><div>The increasing environmental pollution, particularly from heavy metals and hazardous anions, poses a significant threat to global health and ecosystems. The unique structural features of these compounds, including multiple coordination sites, enhanced electron density, favorable steric effects, and stabilized metal-ligand complexes, enable their effective application in both chemosensing and heavy metal remediation. As chemosensors, acyl thiourea derivatives exhibit high sensitivity and selectivity in detecting various cations, anions, and neutral species, making them valuable tools for in situ environmental analysis. Additionally, their ability to efficiently adsorb heavy metals like Cu<sup>2+</sup>, Hg<sup>2+</sup>, Cd<sup>2+</sup>, U<sup>4+</sup>, Pb<sup>2+</sup>, Pt<sup>4+</sup>, and Pd<sup>2+</sup>, along with the removal of Cl<sup>−</sup> from acidic wastewater, demonstrates their practical significance in combating heavy metal pollution. This study highlights the innovative use of acyl thiourea derivatives as versatile tools for addressing the critical issue of environmental pollution, contributing to the advancement of environmental science and technology by offering effective methods for the detection and remediation of environmental pollutants using acyl thioureas.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"12 6","pages":"Article 114279"},"PeriodicalIF":7.4000,"publicationDate":"2024-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Environmental Chemical Engineering","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2213343724024102","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The increasing environmental pollution, particularly from heavy metals and hazardous anions, poses a significant threat to global health and ecosystems. The unique structural features of these compounds, including multiple coordination sites, enhanced electron density, favorable steric effects, and stabilized metal-ligand complexes, enable their effective application in both chemosensing and heavy metal remediation. As chemosensors, acyl thiourea derivatives exhibit high sensitivity and selectivity in detecting various cations, anions, and neutral species, making them valuable tools for in situ environmental analysis. Additionally, their ability to efficiently adsorb heavy metals like Cu2+, Hg2+, Cd2+, U4+, Pb2+, Pt4+, and Pd2+, along with the removal of Cl− from acidic wastewater, demonstrates their practical significance in combating heavy metal pollution. This study highlights the innovative use of acyl thiourea derivatives as versatile tools for addressing the critical issue of environmental pollution, contributing to the advancement of environmental science and technology by offering effective methods for the detection and remediation of environmental pollutants using acyl thioureas.
期刊介绍:
The Journal of Environmental Chemical Engineering (JECE) serves as a platform for the dissemination of original and innovative research focusing on the advancement of environmentally-friendly, sustainable technologies. JECE emphasizes the transition towards a carbon-neutral circular economy and a self-sufficient bio-based economy. Topics covered include soil, water, wastewater, and air decontamination; pollution monitoring, prevention, and control; advanced analytics, sensors, impact and risk assessment methodologies in environmental chemical engineering; resource recovery (water, nutrients, materials, energy); industrial ecology; valorization of waste streams; waste management (including e-waste); climate-water-energy-food nexus; novel materials for environmental, chemical, and energy applications; sustainability and environmental safety; water digitalization, water data science, and machine learning; process integration and intensification; recent developments in green chemistry for synthesis, catalysis, and energy; and original research on contaminants of emerging concern, persistent chemicals, and priority substances, including microplastics, nanoplastics, nanomaterials, micropollutants, antimicrobial resistance genes, and emerging pathogens (viruses, bacteria, parasites) of environmental significance.