{"title":"Synthesis of Ceramic Pigments with Willemite Structure and Their Use for Blue Glazes","authors":"U. A. Kodirova, Z. R. Kadyrova, F. G. Khomidov","doi":"10.1007/s10717-024-00692-z","DOIUrl":null,"url":null,"abstract":"<p>The possibility of isovalent substitution of zinc and cobalt atoms in the structure of willemite Zn<sub>2</sub>SiO<sub>4</sub> was studied. Ceramic pigments with a willemite structure of blue, violet, and light blue colors were synthesized. Samples of blue color were used in the manufacture of glazes. During the synthesis of the pigments, synthetic silicon oxide was replaced by natural quartz sand. The pigments were synthesized by solid-state method at a temperature of 1270°C. The physical and chemical properties of the synthesized blue pigment were determined. In addition, the pigment was tested for use in traditional glazes for the coloring of ceramic products. It was established that the obtained blue pigment provides high aesthetic and decorative characteristics at a relatively low price.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"81 5-6","pages":"252 - 256"},"PeriodicalIF":0.6000,"publicationDate":"2024-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Glass and Ceramics","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s10717-024-00692-z","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0
Abstract
The possibility of isovalent substitution of zinc and cobalt atoms in the structure of willemite Zn2SiO4 was studied. Ceramic pigments with a willemite structure of blue, violet, and light blue colors were synthesized. Samples of blue color were used in the manufacture of glazes. During the synthesis of the pigments, synthetic silicon oxide was replaced by natural quartz sand. The pigments were synthesized by solid-state method at a temperature of 1270°C. The physical and chemical properties of the synthesized blue pigment were determined. In addition, the pigment was tested for use in traditional glazes for the coloring of ceramic products. It was established that the obtained blue pigment provides high aesthetic and decorative characteristics at a relatively low price.
期刊介绍：
Glass and Ceramics reports on advances in basic and applied research and plant production techniques in glass and ceramics. The journal''s broad coverage includes developments in the areas of silicate chemistry, mineralogy and metallurgy, crystal chemistry, solid state reactions, raw materials, phase equilibria, reaction kinetics, physicochemical analysis, physics of dielectrics, and refractories, among others.
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