{"title":"Investigation of compressibility characteristics of coal matrix and its inspiration for CBM extraction","authors":"Hexiang Xu, Jizhao Xu, Cheng Zhai, Ting Liu, Xu Yu, Yangfeng Zheng, Yong Sun, Aikun Chen","doi":"10.1007/s12665-024-11881-y","DOIUrl":null,"url":null,"abstract":"<div><p>Mercury intrusion porosimetry (MIP) is widely used for coal pore structure characterization, however, the matrix compressibility (MC) can lead to overestimated measurement results. Determination of MC is crucial for revealing the influence of pore structure on coalbed methane (CBM) flow behavior. In this study, MIP and low temperature N<sub>2</sub> adsorption (LT-N<sub>2</sub>A) were conducted on 15 coal samples from major coal-producing regions in Northern China. The MIP data were corrected using MC theory, and the effects of coal rank and pore structure on coal MC were analyzed. The influence of MC on fractal dimension was elucidated, and the sensitivity of three fractal models to MC was effectively evaluated. Finally, the impact of MC on the coalbed methane (CBM) exploitation was discussed. The results show that low-rank coals have higher MC than medium/high-rank coals, and the MC coefficient follows a cubic polynomial relationship with coal rank, with two inflection points located at 1.4–2.5%, respectively. Micropores and transition pores are the main contributors to MC, for corrected data, the pore volume of both types of pores decreases significantly. The corrected pore size distribution exhibits better agreement with the LT-N<sub>2</sub>A measurement results, particularly in peak position and size for pores between 5 and 50 nm. This suggests the potential of corrected MIP data to supersede the combined use of MIP and LT-N<sub>2</sub>A data. MC can lead to overestimation of the fractal dimension, with the thermodynamic model showing the lowest sensitivity to MC. After the microfractures in medium/high-rank coal are greatly compressed, the compressional deformation of micropores and transition pores begins to have a significant impact on the CBM transport. The research results are of great significance for deeply understanding the mechanism of CBM transport.</p></div>","PeriodicalId":542,"journal":{"name":"Environmental Earth Sciences","volume":"83 19","pages":""},"PeriodicalIF":2.8000,"publicationDate":"2024-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Earth Sciences","FirstCategoryId":"93","ListUrlMain":"https://link.springer.com/article/10.1007/s12665-024-11881-y","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 0
Abstract
Mercury intrusion porosimetry (MIP) is widely used for coal pore structure characterization, however, the matrix compressibility (MC) can lead to overestimated measurement results. Determination of MC is crucial for revealing the influence of pore structure on coalbed methane (CBM) flow behavior. In this study, MIP and low temperature N2 adsorption (LT-N2A) were conducted on 15 coal samples from major coal-producing regions in Northern China. The MIP data were corrected using MC theory, and the effects of coal rank and pore structure on coal MC were analyzed. The influence of MC on fractal dimension was elucidated, and the sensitivity of three fractal models to MC was effectively evaluated. Finally, the impact of MC on the coalbed methane (CBM) exploitation was discussed. The results show that low-rank coals have higher MC than medium/high-rank coals, and the MC coefficient follows a cubic polynomial relationship with coal rank, with two inflection points located at 1.4–2.5%, respectively. Micropores and transition pores are the main contributors to MC, for corrected data, the pore volume of both types of pores decreases significantly. The corrected pore size distribution exhibits better agreement with the LT-N2A measurement results, particularly in peak position and size for pores between 5 and 50 nm. This suggests the potential of corrected MIP data to supersede the combined use of MIP and LT-N2A data. MC can lead to overestimation of the fractal dimension, with the thermodynamic model showing the lowest sensitivity to MC. After the microfractures in medium/high-rank coal are greatly compressed, the compressional deformation of micropores and transition pores begins to have a significant impact on the CBM transport. The research results are of great significance for deeply understanding the mechanism of CBM transport.
汞侵入孔隙模拟法(MIP)被广泛用于煤炭孔隙结构表征,但是基质可压缩性(MC)会导致测量结果被高估。测定 MC 对于揭示孔隙结构对煤层气流动行为的影响至关重要。本研究对来自中国北方主要产煤区的 15 个煤样进行了 MIP 和低温 N2 吸附(LT-N2A)测试。利用 MC 理论对 MIP 数据进行了校正,并分析了煤炭等级和孔隙结构对煤炭 MC 的影响。阐明了 MC 对分形维度的影响,并有效评估了三种分形模型对 MC 的敏感性。最后,讨论了 MC 对煤层气开采的影响。结果表明,低阶煤的 MC 值高于中/高阶煤,MC 系数与煤阶呈三次多项式关系,两个拐点分别位于 1.4%-2.5%。微孔和过渡孔隙是产生 MC 的主要原因,对于校正后的数据,这两类孔隙的孔隙体积都明显减小。校正后的孔径分布与 LT-N2A 测量结果的一致性更好,尤其是在 5 至 50 nm 之间的孔的峰值位置和尺寸方面。这表明校正后的 MIP 数据有可能取代 MIP 和 LT-N2A 数据的组合使用。MC 会导致高估分形维度,而热力学模型对 MC 的敏感性最低。中/高阶煤中的微裂隙被大幅压缩后,微孔和过渡孔隙的压缩变形开始对煤层气运移产生显著影响。该研究成果对深入理解煤层气运移机理具有重要意义。
期刊介绍:
Environmental Earth Sciences is an international multidisciplinary journal concerned with all aspects of interaction between humans, natural resources, ecosystems, special climates or unique geographic zones, and the earth:
Water and soil contamination caused by waste management and disposal practices
Environmental problems associated with transportation by land, air, or water
Geological processes that may impact biosystems or humans
Man-made or naturally occurring geological or hydrological hazards
Environmental problems associated with the recovery of materials from the earth
Environmental problems caused by extraction of minerals, coal, and ores, as well as oil and gas, water and alternative energy sources
Environmental impacts of exploration and recultivation – Environmental impacts of hazardous materials
Management of environmental data and information in data banks and information systems
Dissemination of knowledge on techniques, methods, approaches and experiences to improve and remediate the environment
In pursuit of these topics, the geoscientific disciplines are invited to contribute their knowledge and experience. Major disciplines include: hydrogeology, hydrochemistry, geochemistry, geophysics, engineering geology, remediation science, natural resources management, environmental climatology and biota, environmental geography, soil science and geomicrobiology.