Optimized Dewaxed Honeycomb Powder as a Promising and Eco-Friendly Alternative for the Removal of Malachite Green through Fixed Bed Column

IF 0.5 4区 化学 Q4 CHEMISTRY, ANALYTICAL
Roshni Kumari, Md. Adnan Khan, Mithilesh Mahto, Md. Atif Qaiyum, Jhilirani Mohanta, Banashree Dey, Priyanka Priyadarsini Samal, B. Sambasivaiah, Soumen Dey
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Abstract

A fixed-bed column study for the removal of malachite green (MG) from the aqueous phase was demonstrated using strategically dewaxed honeycomb powder (HCP). The removal efficiency was tested at several working parameters of the column, in particular, the column bed height, initial dye concentration, working pH, and the flow rate. Breakthrough curves have been plotted using the throughput volume versus concentration ratio for different parameters to identify the pathway of uptake. Thomas and bed depth service time (BDST) kinetic models have been applied to obtain the rate constants and the uptake capacity. The BDST model suggests an adsorption capacity of 196.28 mg L–1. The column performance was seen to vary with solution pH and was found favourable at higher pH values. The adsorption rate decreases with increasing flow rate but increases with increasing concentration of the dye. Easy regeneration ensures multi-cycle operations. The mechanism of dye adsorption by HCP has been proposed as a blend of electrostatic attraction and weak forces. Henceforth, the use of HCP for the removal of MG in column mode may be extrapolated to serve as a promising agent in the treatment of dye-containing water and wastewater.

Abstract Image

优化的脱蜡蜂窝状粉末是通过固定床色谱柱去除孔雀石绿的一种前景广阔的环保型替代品
使用战略性脱蜡蜂巢粉末(HCP)进行了一项固定床色谱柱研究,以去除水相中的孔雀石绿(MG)。在柱的几个工作参数下测试了去除效率,特别是柱床高度、初始染料浓度、工作 pH 值和流速。利用不同参数下的吞吐量与浓度比绘制了突破曲线,以确定吸收途径。应用托马斯和床层深度服务时间(BDST)动力学模型得出了速率常数和吸收能力。BDST 模型表明吸附容量为 196.28 毫克/升。吸附柱的性能随溶液 pH 值的变化而变化,pH 值越高,吸附性能越好。吸附率随着流速的增加而降低,但随着染料浓度的增加而提高。易于再生确保了多循环操作。HCP 吸附染料的机理被认为是静电引力和弱力的混合作用。因此,在柱模式下使用 HCP 去除 MG,可以推断出它在处理含染料的水和废水方面具有广阔的前景。
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来源期刊
Journal of Water Chemistry and Technology
Journal of Water Chemistry and Technology CHEMISTRY, APPLIED-CHEMISTRY, ANALYTICAL
自引率
0.00%
发文量
51
审稿时长
>12 weeks
期刊介绍: Journal of Water Chemistry and Technology focuses on water and wastewater treatment, water pollution monitoring, water purification, and similar topics. The journal publishes original scientific theoretical and experimental articles in the following sections: new developments in the science of water; theoretical principles of water treatment and technology; physical chemistry of water treatment processes; analytical water chemistry; analysis of natural and waste waters; water treatment technology and demineralization of water; biological methods of water treatment; and also solicited critical reviews summarizing the latest findings. The journal welcomes manuscripts from all countries in the English or Ukrainian language. All manuscripts are peer-reviewed.
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