T. S. Hubetska, V. Ya. Demchenko, N. G. Kobylinska
{"title":"Chemical Design of Mg(II)/Fe(III)-Layered Double Hydroxides and Their Sorption Properties Toward Ibuprofen","authors":"T. S. Hubetska, V. Ya. Demchenko, N. G. Kobylinska","doi":"10.1007/s11237-024-09810-y","DOIUrl":null,"url":null,"abstract":"<p>The features of the synthesis and the structure formation of homogenous phases of Mg(II),Fe(III)-layered double hydroxides with different Mg/Fe ratio in the reaction mixtures have been investigated. The effect of synthesis conditions of the materials, arrangement and molar ratio of the cations in a brucite-like layer, and polytypes of crystalline structure on the sorption properties toward ibuprofen has been studied. The sorption isotherms of ibuprofen on the synthesized sorbents at pH<sub>0</sub> = 7,0 are satisfyingly fitted by the Langmuir model. The influence of the Mg<sup>2+</sup>/Fe<sup>3+</sup> molar ratio and, respectively, the dimensions of the interlayer space on the maximum adsorption capacities toward ibuprofen in the aqueous solution is not observed. These results can be explained by the interaction of the adsorbate with the surface hydroxyl groups of brucite-like layers, as well as complexing reactions with structure-forming cations of the obtained sorbents.</p>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":"60 1","pages":"64 - 75"},"PeriodicalIF":0.7000,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical and Experimental Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11237-024-09810-y","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The features of the synthesis and the structure formation of homogenous phases of Mg(II),Fe(III)-layered double hydroxides with different Mg/Fe ratio in the reaction mixtures have been investigated. The effect of synthesis conditions of the materials, arrangement and molar ratio of the cations in a brucite-like layer, and polytypes of crystalline structure on the sorption properties toward ibuprofen has been studied. The sorption isotherms of ibuprofen on the synthesized sorbents at pH0 = 7,0 are satisfyingly fitted by the Langmuir model. The influence of the Mg2+/Fe3+ molar ratio and, respectively, the dimensions of the interlayer space on the maximum adsorption capacities toward ibuprofen in the aqueous solution is not observed. These results can be explained by the interaction of the adsorbate with the surface hydroxyl groups of brucite-like layers, as well as complexing reactions with structure-forming cations of the obtained sorbents.
期刊介绍:
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.