Cluster Self-Organization of Intermetallic Systems: Clusters-Precursors K3, K4, and K6 for the Self-Assembly of RbNa8Ga3As6-oP72, Sr2Ca4In3Ge6-oP56, and Sr8Li4In4Ge8-oP24 Crystal Structures

IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, CERAMICS
V. Ya. Shevchenko, G. D. Ilyushin
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引用次数: 0

Abstract

Using computer methods (the ToposPro software package), combinatorial-topological analysis and modeling of self-assembly of the following crystal structures are carried out: RbNa8Ga3As6-oP72 (a = 22.843Å, b = 4.789 c = 16.861 Å, V = 1844.6 Å3, Pnma), Sr2Ca4In3Ge6-oP56 (a = 13.243 Å, b = 4.460 Å, c = 23.505 Å, V = 1388.47 Å3, Pnma), and Sr8Li4In4Ge8-oP24 (a = 7.503 Å, b = 4.619 Å, c = 17.473 Å, V = 605.6 Å3, Pnma). For the RbNa8Ga3As6-oP72 crystal structure, 93 variants of a cluster representation of a 3D atomic mesh with the number of structural units of 3, 4, and 6 are established. A variant of self-assembly involving three types of clusters-precursors is considered: double tetrahedra K6(4a) = 0@6 (Rb2Na2As2) and K6(4b) = 0@6 (Na4As2) with symmetry g = –1, tetrahedron K4(8d) = 0@4(Na3As), two triple rings K3-1 = 0@3(NaGaAs), and Ga and As spacer atoms. For the Sr2Ca4In3Ge6-oP56 crystal structure, 43 variants of a cluster representation of a 3D atomic mesh with the number of structural units of 3, 4, and 6 are established. A variant of self-assembly of a crystal structure involving three types of clusters-precursors from double tetrahedra K6(4a) = 0@6 (Sr) 2In2Ge2) and K6(4b) = 0@6 (Ca2In2Ge2) with symmetry g = –1, double tetrahedra K6(4c) = 0@6 (SrCa2InGe2), and Ge2 and Ge4 spacer atoms is considered. For the Sr8Li4In4Ge8-oP24 crystal structure, three variants of a cluster representation of a 3D atomic mesh with two structural units are established. A variant of the self-assembly of a crystal structure involving two types of clusters-precursors in the form of double tetrahedra K6 = (Sr2Li2Ge2) with symmetry g = –1 and triple rings K3 = 0@3 (SrInGe) is considered. The symmetry and topological code of the processes of self-assembly of 3D structures from clusters-precursors are reconstructed in the following form: primary chain → layer → framework.

Abstract Image

金属间体系的簇自组织:用于自组装 RbNa8Ga3As6-oP72、Sr2Ca4In3Ge6-oP56 和 Sr8Li4In4Ge8-oP24 晶体结构的簇-前体 K3、K4 和 K6
利用计算机方法(ToposPro 软件包),对下列晶体结构进行了组合-拓扑分析和自组装建模:RbNa8Ga3As6-oP72(a = 22.843 Å,b = 4.789 c = 16.861 Å,V = 1844.6 Å3,Pnma)、Sr2Ca4In3Ge6-oP56(a = 13.243 Å,b = 4.460 Å,c = 23.505 Å,V = 1388.47 Å3,Pnma),以及 Sr8Li4In4Ge8-oP24(a = 7.503 Å,b = 4.619 Å,c = 17.473 Å,V = 605.6 Å3,Pnma)。对于 RbNa8Ga3As6-oP72 晶体结构,建立了 93 种结构单元数为 3、4 和 6 的三维原子网格簇表示变体。其中一种自组装变体涉及三种类型的簇前驱体:对称性为 g = -1 的双四面体 K6(4a) = 0@6(Rb2Na2As2)和 K6(4b) = 0@6(Na4As2)、四面体 K4(8d) = 0@4(Na3As)、两个三环 K3-1 = 0@3(NaGaAs)以及镓和砷间隔原子。对于 Sr2Ca4In3Ge6-oP56 晶体结构,建立了 43 种结构单元数为 3、4 和 6 的三维原子网簇表示变体。研究考虑了一种晶体结构自组装变体,它涉及三种类型的簇--对称性为 g = -1 的双四面体 K6(4a) = 0@6 (Sr)2In2Ge2)和 K6(4b) = 0@6 (Ca2In2Ge2)的前驱体、双四面体 K6(4c) = 0@6 (SrCa2InGe2)以及 Ge2 和 Ge4 间距原子。对于 Sr8Li4In4Ge8-oP24 晶体结构,建立了三种具有两个结构单元的三维原子网格的簇表示变体。考虑了涉及两类簇的晶体结构自组装变体--对称性为 g = -1 的双四面体 K6 = (Sr2Li2Ge2)和三环 K3 = 0@3 (SrInGe)形式的前驱体。由团簇-前驱体自组装三维结构过程的对称性和拓扑代码按以下形式重构:主链 → 层 → 框架。
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来源期刊
Glass Physics and Chemistry
Glass Physics and Chemistry 工程技术-材料科学:硅酸盐
CiteScore
1.20
自引率
14.30%
发文量
46
审稿时长
6-12 weeks
期刊介绍: Glass Physics and Chemistry presents results of research on the inorganic and physical chemistry of glass, ceramics, nanoparticles, nanocomposites, and high-temperature oxides and coatings. The journal welcomes manuscripts from all countries in the English or Russian language.
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