Microstructural evolution in lithium plating process and its effect on the calendar storage life

IF 9.5 2区 材料科学 Q1 CHEMISTRY, PHYSICAL
Ki Hwan Koh, Dong Ju Lee, Anthony Mu, Kangwoon Kim, Taehee Kim, Zheng Chen
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Abstract

The growing demand for electric vehicles highlights the need for energy storage solutions with higher densities, spotlighting Li metal anodes as potential successors to traditional Li-ion batteries (LIBs). Achieving longer calendar aging life for Li metal anodes is crucial for their practical use, given their propensity for corrosion due to a low redox potential, which leads to compromised cycling stability and significant capacity loss during storage. Recent research investigated that this susceptibility is mainly dependent on the surface area of Li metal anode and the properties of the solid electrolyte interphase (SEI), particularly its stability and growth rate. Our research adds to this understanding by demonstrating that the amount of Li plating is a key factor in its corrosion during open-circuit storage, as assessed across various electrolytes. We discovered that increasing the Li plating amount effectively reduces Coulombic efficiency (C.E.) loss during aging, due to a lower surface area-to-Li ratio. This implies that the choice of electrolyte for optimal storage life should consider the amount of Li plating, with higher capacities promoting better storage characteristics.

镀锂过程中的微结构演变及其对日历存储寿命的影响
电动汽车需求的不断增长凸显了对更高密度储能解决方案的需求,这也使金属锂阳极成为传统锂离子电池(LIB)的潜在替代品。由于锂金属阳极的氧化还原电位较低,容易受到腐蚀,从而导致循环稳定性受到影响,并在存储过程中出现显著的容量损失,因此延长锂金属阳极的日历老化寿命对其实际应用至关重要。最近的研究表明,这种易腐蚀性主要取决于锂金属阳极的表面积和固体电解质相间层(SEI)的特性,特别是其稳定性和生长速度。我们的研究通过在各种电解质中评估锂镀层的数量是影响其开路存储期间腐蚀性的关键因素,进一步加深了对这一问题的理解。我们发现,由于表面积与锂的比率降低,增加镀锂量可有效减少老化过程中库仑效率(C.E.)的损失。这意味着在选择电解质以获得最佳存储寿命时应考虑锂镀层的数量,容量越高,存储特性越好。
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来源期刊
Nano Research
Nano Research 化学-材料科学:综合
CiteScore
14.30
自引率
11.10%
发文量
2574
审稿时长
1.7 months
期刊介绍: Nano Research is a peer-reviewed, international and interdisciplinary research journal that focuses on all aspects of nanoscience and nanotechnology. It solicits submissions in various topical areas, from basic aspects of nanoscale materials to practical applications. The journal publishes articles on synthesis, characterization, and manipulation of nanomaterials; nanoscale physics, electrical transport, and quantum physics; scanning probe microscopy and spectroscopy; nanofluidics; nanosensors; nanoelectronics and molecular electronics; nano-optics, nano-optoelectronics, and nano-photonics; nanomagnetics; nanobiotechnology and nanomedicine; and nanoscale modeling and simulations. Nano Research offers readers a combination of authoritative and comprehensive Reviews, original cutting-edge research in Communication and Full Paper formats. The journal also prioritizes rapid review to ensure prompt publication.
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