New Features of the H2SO4–HNO3 System in the Synthesis of Adamantanecarboxylic Acids

IF 0.9 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Russian Journal of General Chemistry Pub Date : 2024-10-04 DOI:10.1134/S1070363224080024

E. A. Ivleva, D. V. Zvereva, Yu. N. Klimochkin

引用次数: 0

Abstract

New methods for the direct preparation of 3-hydroxy-1-adamantanecarboxylic acid and 1,3-adamantanedicarboxylic acid from 1-adamantyl halides was developed. The one-pot methods are based on the sequential combination of the Koch–Haaf and oxidation reactions in a H₂SO₄–HNO₃ mixture. This study proposes an improved method for the preparation of 1-adamantanecarboxylic acids from 1-adamantyl halides.

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H2SO4-HNO3 系统在合成金刚烷甲酸中的新特点

开发了从 1-金刚烷卤化物直接制备 3-羟基-1-金刚烷羧酸和 1,3-金刚烷二羧酸的新方法。这种一锅法是在 H2SO4-HNO3 混合物中将 Koch-Haaf 反应和氧化反应顺序结合起来。本研究提出了一种从 1-金刚烷基卤化物制备 1-金刚烷甲酸的改进方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Russian Journal of General Chemistry 化学-化学综合

CiteScore

1.40

自引率

22.20%

发文量

252

审稿时长

2-4 weeks

期刊介绍： Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.